Abstract
The hexane-carbon dioxide reaction was carried out at 1173 K in order to study the catalytic properties of alkaline earth oxides and the reaction intermediate for the gasification. The catalytic activities of these oxides depended upon both the nature of the alkaline earth and the starting material. Magnesium oxide, prepared from the basic carbonate or calcium oxide, showed high catalytic activity, whereas strontium and barium oxides were inactive due to an inability to form the carbonaceous intermediate. Hexane was thermally decomposed in the gas phase to give C1C3 hydrocarbons, hydrogen and a carbon precursor. C1C3 hydrocarbons scarcely interacted with the catalyst. The carbon precursor was captured by the active catalyst to give carbon which was the intermediate for catalytic gasification.
| Original language | English |
|---|---|
| Pages (from-to) | 217-227 |
| Number of pages | 11 |
| Journal | Applied Catalysis |
| Volume | 37 |
| Issue number | C |
| DOIs | |
| Publication status | Published - 1988 |
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Hexane-carbon dioxide reaction catalyzed by alkaline earth oxides. I. Catalytic Behaviour and Intermediate. / Matsukata, Masahiko; Sekine, S.; Kobayashi, K.; Kikuchi, E.; Morita, Y.
In: Applied Catalysis, Vol. 37, No. C, 1988, p. 217-227.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Hexane-carbon dioxide reaction catalyzed by alkaline earth oxides. I. Catalytic Behaviour and Intermediate
AU - Matsukata, Masahiko
AU - Sekine, S.
AU - Kobayashi, K.
AU - Kikuchi, E.
AU - Morita, Y.
PY - 1988
Y1 - 1988
N2 - The hexane-carbon dioxide reaction was carried out at 1173 K in order to study the catalytic properties of alkaline earth oxides and the reaction intermediate for the gasification. The catalytic activities of these oxides depended upon both the nature of the alkaline earth and the starting material. Magnesium oxide, prepared from the basic carbonate or calcium oxide, showed high catalytic activity, whereas strontium and barium oxides were inactive due to an inability to form the carbonaceous intermediate. Hexane was thermally decomposed in the gas phase to give C1C3 hydrocarbons, hydrogen and a carbon precursor. C1C3 hydrocarbons scarcely interacted with the catalyst. The carbon precursor was captured by the active catalyst to give carbon which was the intermediate for catalytic gasification.
AB - The hexane-carbon dioxide reaction was carried out at 1173 K in order to study the catalytic properties of alkaline earth oxides and the reaction intermediate for the gasification. The catalytic activities of these oxides depended upon both the nature of the alkaline earth and the starting material. Magnesium oxide, prepared from the basic carbonate or calcium oxide, showed high catalytic activity, whereas strontium and barium oxides were inactive due to an inability to form the carbonaceous intermediate. Hexane was thermally decomposed in the gas phase to give C1C3 hydrocarbons, hydrogen and a carbon precursor. C1C3 hydrocarbons scarcely interacted with the catalyst. The carbon precursor was captured by the active catalyst to give carbon which was the intermediate for catalytic gasification.
UR - http://www.scopus.com/inward/record.url?scp=0023962767&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0023962767&partnerID=8YFLogxK
U2 - 10.1016/S0166-9834(00)80762-9
DO - 10.1016/S0166-9834(00)80762-9
M3 - Article
VL - 37
SP - 217
EP - 227
JO - Applied Catalysis
JF - Applied Catalysis
SN - 0166-9834
IS - C
ER -