The oxygen-binding affinity of the cobalt-picketfence-porphyrin (CoP) ligated with imidazole was enhanced in the presence of an additive which forms a hydrogen-bond with the ligated imidazole. The CoP complex with poly(4(5)-vinylimidazole-co-octylmethacrylate) rapidly and reversibly bound oxygen and showed very high oxygen-binding affinity: The oxygen transport in the CoP-polymer membrane was efficiently facilitated.
|Number of pages||6|
|Journal||Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals|
|Publication status||Published - 2000|
ASJC Scopus subject areas
- Condensed Matter Physics
High oxygen-binding affinity of poly(4-vinylimidazole-co-octylmethacrylate)-cobaltporphyrin complex : effect of hydrogen-bond at the imidazole residue. / Nishide, Hiroyuki; Kato, Aiko; Tsuchida, Eishun.In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 342, 2000, p. 249-254.
Research output: Contribution to journal › Article