Highly enantioselective preparation of tricyclo[4.4.0.05,7]decene derivatives via catalytic asymmetric intramolecular cyclopropanation reactions of α-diazo-β-keto esters

Ryoji Ida; Masahisa Nakada

doi:10.1016/j.tetlet.2007.05.046

Highly enantioselective preparation of tricyclo[4.4.0.0^5,7]decene derivatives via catalytic asymmetric intramolecular cyclopropanation reactions of α-diazo-β-keto esters

Ryoji Ida, Masahisa Nakada

School of Advanced Science and Engineering

Research output: Contribution to journal › Article

25 Citations (Scopus)

Abstract

The enantioselective preparation of the tricyclo[4.4.0.0^5,7]dec-2-ene derivatives via the catalytic asymmetric intramolecular cyclopropanation (CAIMCP) reactions of α-diazo-β-keto esters with excellent ee (95-98% ee) is described. The chiral building blocks reported herein would be versatile intermediates for enantioselective natural products synthesis.

Original language	English
Pages (from-to)	4855-4859
Number of pages	5
Journal	Tetrahedron Letters
Volume	48
Issue number	28
DOIs	https://doi.org/10.1016/j.tetlet.2007.05.046
Publication status	Published - 2007 Jul 9

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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Ida, R., & Nakada, M. (2007). Highly enantioselective preparation of tricyclo[4.4.0.0^5,7]decene derivatives via catalytic asymmetric intramolecular cyclopropanation reactions of α-diazo-β-keto esters. Tetrahedron Letters, 48(28), 4855-4859. https://doi.org/10.1016/j.tetlet.2007.05.046

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abstract = "The enantioselective preparation of the tricyclo[4.4.0.05,7]dec-2-ene derivatives via the catalytic asymmetric intramolecular cyclopropanation (CAIMCP) reactions of α-diazo-β-keto esters with excellent ee (95-98% ee) is described. The chiral building blocks reported herein would be versatile intermediates for enantioselective natural products synthesis.",

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