Highly enantioselective synthesis of silahelicenes using Ir-catalyzed [2+2+2] cycloaddition

Takanori Shibata, Toshifumi Uchiyama, Yusuke Yoshinami, Satoshi Takayasu, Kyoji Tsuchikama, Kohei Endo

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    Abstract

    Silahelicenes, which contain two silole moieties in a helically chiral structure, were synthesized by a chiral Ir-catalyzed intermolecular [2+2+2] cycloaddition of tetraynes with diynes along with a Ni-mediated intramolecular [2+2+2] cycloaddition. The photophysical properties of the obtained highly enantiomerically enriched silahelicenes (up to 93% ee) were also measured.

    Original languageEnglish
    Pages (from-to)1311-1313
    Number of pages3
    JournalChemical Communications
    Volume48
    Issue number9
    DOIs
    Publication statusPublished - 2012 Jan 30

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    ASJC Scopus subject areas

    • Metals and Alloys
    • Materials Chemistry
    • Surfaces, Coatings and Films
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Catalysis
    • Chemistry(all)

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