Abstract
A polypyrrole (PPy) film grows with the aid of a precoated nitrile rubber (NBR) by an electropolymerization method was found to show a highly enhanced anion doping-undoping process because of its oriented grown structure. In the procedure of the preparation of this special electrode (Pt/NBR/PPy), a NBR film, originally insulating and soluble in electrolyte solution of acetonitrile(AN)/ LiClO//4, played the role of a host polymer regulating the growth of PPy film in the direction perpendicular to the substrate. The guest polymer of PPy film grew through the fine channels etched by the penetration of the electrolyte into the NBR films during electropolymerization.
| Original language | English |
|---|---|
| Pages (from-to) | 2479-2483 |
| Number of pages | 5 |
| Journal | Journal of the Electrochemical Society |
| Volume | 134 |
| Issue number | 10 |
| Publication status | Published - 1987 Oct |
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ASJC Scopus subject areas
- Electrochemistry
- Surfaces, Coatings and Films
- Surfaces and Interfaces
Cite this
HIGHLY ENHANCED ANION DOPING-UNDOPING PROCESS AT THE POLYPYRROLE ELECTRODE OF REGULATED MORPHOLOGY PREPARED WITH THE AID OF INSULATING NBR FILM. / Naoi, Katsuhiko; Osaka, Tetsuya.
In: Journal of the Electrochemical Society, Vol. 134, No. 10, 10.1987, p. 2479-2483.Research output: Contribution to journal › Article
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TY - JOUR
T1 - HIGHLY ENHANCED ANION DOPING-UNDOPING PROCESS AT THE POLYPYRROLE ELECTRODE OF REGULATED MORPHOLOGY PREPARED WITH THE AID OF INSULATING NBR FILM.
AU - Naoi, Katsuhiko
AU - Osaka, Tetsuya
PY - 1987/10
Y1 - 1987/10
N2 - A polypyrrole (PPy) film grows with the aid of a precoated nitrile rubber (NBR) by an electropolymerization method was found to show a highly enhanced anion doping-undoping process because of its oriented grown structure. In the procedure of the preparation of this special electrode (Pt/NBR/PPy), a NBR film, originally insulating and soluble in electrolyte solution of acetonitrile(AN)/ LiClO//4, played the role of a host polymer regulating the growth of PPy film in the direction perpendicular to the substrate. The guest polymer of PPy film grew through the fine channels etched by the penetration of the electrolyte into the NBR films during electropolymerization.
AB - A polypyrrole (PPy) film grows with the aid of a precoated nitrile rubber (NBR) by an electropolymerization method was found to show a highly enhanced anion doping-undoping process because of its oriented grown structure. In the procedure of the preparation of this special electrode (Pt/NBR/PPy), a NBR film, originally insulating and soluble in electrolyte solution of acetonitrile(AN)/ LiClO//4, played the role of a host polymer regulating the growth of PPy film in the direction perpendicular to the substrate. The guest polymer of PPy film grew through the fine channels etched by the penetration of the electrolyte into the NBR films during electropolymerization.
UR - http://www.scopus.com/inward/record.url?scp=0023430313&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0023430313&partnerID=8YFLogxK
M3 - Article
VL - 134
SP - 2479
EP - 2483
JO - Journal of the Electrochemical Society
JF - Journal of the Electrochemical Society
SN - 0013-4651
IS - 10
ER -