Highly stable gold(III) complex with a hydantoin ligand in alkaline media

Kenichi Oyaizu, Yutaka Ohtani, Asako Shiozawa, Kenji Sugawara, Takashi Saito, Makoto Yuasa

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

A novel gold(III) complex with a monodentate 5,5-dimethylhydantoin ligand, [Au(dmh)4]-, is square planar in geometry, inert and highly stable in alkaline solutions because of soft acid-base interactions, and electrochemically reduced near -0.3 V vs Ag/AgCl to give a gold(0) film with a high current efficiency.

Original languageEnglish
Pages (from-to)6915-6917
Number of pages3
JournalInorganic Chemistry
Volume44
Issue number20
DOIs
Publication statusPublished - 2005 Oct 3
Externally publishedYes

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Hydantoins
Gold
gold
Ligands
ligands
high current
acids
Acids
Geometry
geometry
interactions
5,5-dimethylhydantoin

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Oyaizu, K., Ohtani, Y., Shiozawa, A., Sugawara, K., Saito, T., & Yuasa, M. (2005). Highly stable gold(III) complex with a hydantoin ligand in alkaline media. Inorganic Chemistry, 44(20), 6915-6917. https://doi.org/10.1021/ic050515x

Highly stable gold(III) complex with a hydantoin ligand in alkaline media. / Oyaizu, Kenichi; Ohtani, Yutaka; Shiozawa, Asako; Sugawara, Kenji; Saito, Takashi; Yuasa, Makoto.

In: Inorganic Chemistry, Vol. 44, No. 20, 03.10.2005, p. 6915-6917.

Research output: Contribution to journalArticle

Oyaizu, K, Ohtani, Y, Shiozawa, A, Sugawara, K, Saito, T & Yuasa, M 2005, 'Highly stable gold(III) complex with a hydantoin ligand in alkaline media', Inorganic Chemistry, vol. 44, no. 20, pp. 6915-6917. https://doi.org/10.1021/ic050515x
Oyaizu, Kenichi ; Ohtani, Yutaka ; Shiozawa, Asako ; Sugawara, Kenji ; Saito, Takashi ; Yuasa, Makoto. / Highly stable gold(III) complex with a hydantoin ligand in alkaline media. In: Inorganic Chemistry. 2005 ; Vol. 44, No. 20. pp. 6915-6917.
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