Hydrogen absorption and thermal desorption behavior of Ni-Ti superelastic alloy immersed in neutral NaCl and NaF solutions under applied potentia

Asahi Ota, Yushin Yazaki, Ken'ichi Yokoyama, Jun'ichi Sakai

    Research output: Contribution to journalArticle

    9 Citations (Scopus)

    Abstract

    The hydrogen absorption and thermal desorption behavior of Ni-Ti superelastic alloy immersed in neutral NaCl and NaF aqueous solutions at 25°C under an applied cathodic potential for 2 h have been systematically investigated by hydrogen thermal desorption analysis. The critical potential for hydrogen absorption is independent of the type and concentration of solution. The amount of absorbed hydrogen increases with decreasing applied potential, although it is only slightly changed by the type of solution. The amount of hydrogen desorbed at low temperatures, for the alloy immersed in NaF solutions, is larger than those in NaCl solutions, suggesting that the type of solution affects the hydrogen states in the alloy. The present results indicate that for Ni-Ti superelastic alloy, compared with titanium and its alloys, the critical potential for hydrogen absorption is located in a more noble direction, and the amount of absorbed hydrogen is large in NaCl and NaF solutions. Thus, the hydrogen embrittlement of Ni-Ti superelastic alloy probably occurs more readily than those of titanium and its alloys in NaCl and NaF solutions.

    Original languageEnglish
    Pages (from-to)1843-1849
    Number of pages7
    JournalMaterials Transactions
    Volume50
    Issue number7
    DOIs
    Publication statusPublished - 2009 Jul

    Fingerprint

    Thermal desorption
    Hydrogen
    desorption
    hydrogen
    titanium alloys
    Titanium
    Titanium alloys
    hydrogen embrittlement
    Hydrogen embrittlement
    titanium nickelide
    aqueous solutions

    Keywords

    • Corrosion
    • Hydrogen embrittlement
    • Nitinol
    • Shape memory alloy

    ASJC Scopus subject areas

    • Materials Science(all)
    • Condensed Matter Physics
    • Mechanical Engineering
    • Mechanics of Materials

    Cite this

    Hydrogen absorption and thermal desorption behavior of Ni-Ti superelastic alloy immersed in neutral NaCl and NaF solutions under applied potentia. / Ota, Asahi; Yazaki, Yushin; Yokoyama, Ken'ichi; Sakai, Jun'ichi.

    In: Materials Transactions, Vol. 50, No. 7, 07.2009, p. 1843-1849.

    Research output: Contribution to journalArticle

    Ota, Asahi ; Yazaki, Yushin ; Yokoyama, Ken'ichi ; Sakai, Jun'ichi. / Hydrogen absorption and thermal desorption behavior of Ni-Ti superelastic alloy immersed in neutral NaCl and NaF solutions under applied potentia. In: Materials Transactions. 2009 ; Vol. 50, No. 7. pp. 1843-1849.
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    abstract = "The hydrogen absorption and thermal desorption behavior of Ni-Ti superelastic alloy immersed in neutral NaCl and NaF aqueous solutions at 25°C under an applied cathodic potential for 2 h have been systematically investigated by hydrogen thermal desorption analysis. The critical potential for hydrogen absorption is independent of the type and concentration of solution. The amount of absorbed hydrogen increases with decreasing applied potential, although it is only slightly changed by the type of solution. The amount of hydrogen desorbed at low temperatures, for the alloy immersed in NaF solutions, is larger than those in NaCl solutions, suggesting that the type of solution affects the hydrogen states in the alloy. The present results indicate that for Ni-Ti superelastic alloy, compared with titanium and its alloys, the critical potential for hydrogen absorption is located in a more noble direction, and the amount of absorbed hydrogen is large in NaCl and NaF solutions. Thus, the hydrogen embrittlement of Ni-Ti superelastic alloy probably occurs more readily than those of titanium and its alloys in NaCl and NaF solutions.",
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    AU - Sakai, Jun'ichi

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    N2 - The hydrogen absorption and thermal desorption behavior of Ni-Ti superelastic alloy immersed in neutral NaCl and NaF aqueous solutions at 25°C under an applied cathodic potential for 2 h have been systematically investigated by hydrogen thermal desorption analysis. The critical potential for hydrogen absorption is independent of the type and concentration of solution. The amount of absorbed hydrogen increases with decreasing applied potential, although it is only slightly changed by the type of solution. The amount of hydrogen desorbed at low temperatures, for the alloy immersed in NaF solutions, is larger than those in NaCl solutions, suggesting that the type of solution affects the hydrogen states in the alloy. The present results indicate that for Ni-Ti superelastic alloy, compared with titanium and its alloys, the critical potential for hydrogen absorption is located in a more noble direction, and the amount of absorbed hydrogen is large in NaCl and NaF solutions. Thus, the hydrogen embrittlement of Ni-Ti superelastic alloy probably occurs more readily than those of titanium and its alloys in NaCl and NaF solutions.

    AB - The hydrogen absorption and thermal desorption behavior of Ni-Ti superelastic alloy immersed in neutral NaCl and NaF aqueous solutions at 25°C under an applied cathodic potential for 2 h have been systematically investigated by hydrogen thermal desorption analysis. The critical potential for hydrogen absorption is independent of the type and concentration of solution. The amount of absorbed hydrogen increases with decreasing applied potential, although it is only slightly changed by the type of solution. The amount of hydrogen desorbed at low temperatures, for the alloy immersed in NaF solutions, is larger than those in NaCl solutions, suggesting that the type of solution affects the hydrogen states in the alloy. The present results indicate that for Ni-Ti superelastic alloy, compared with titanium and its alloys, the critical potential for hydrogen absorption is located in a more noble direction, and the amount of absorbed hydrogen is large in NaCl and NaF solutions. Thus, the hydrogen embrittlement of Ni-Ti superelastic alloy probably occurs more readily than those of titanium and its alloys in NaCl and NaF solutions.

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