Abstract
The sulfonic acid (SO3H) group was attached to polyethylene by radiation-induced graft polymerization of sodium p-styrenesulfonate and compared with the SO3H group introduced into the polystyrene chain cross-linked with divinylbenzene. The catalytic activities of the SO3H group were measured in a batch mode for the hydrolysis of methyl acetate and sucrose. The temperature dependence of the reaction rate constants for the hydrolysis was determined. For the hydrolysis of methyl acetate, the SO3H group anchored to the grafted polymer chain had the same activity as the SO3H group introduced into the cross-linked polymer chain. On the other hand, the graft-type acid catalyst had about 10 times the hydrolytic activity for sucrose as the cross-linked acid catalyst.
| Original language | English |
|---|---|
| Pages (from-to) | 2215-2219 |
| Number of pages | 5 |
| Journal | Industrial and Engineering Chemistry Research |
| Volume | 33 |
| Issue number | 9 |
| Publication status | Published - 1994 Sep |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemical Engineering (miscellaneous)
- Environmental Science(all)
- Polymers and Plastics
Cite this
Hydrolysis of methyl acetate and sucrose in SO3H-group-containing grafted polymer chains prepared by radiation-induced graft polymerization. / Mizota, Tomotoshi; Tsuneda, Satoshi; Saito, Kyoichi; Sugo, Takanobu.
In: Industrial and Engineering Chemistry Research, Vol. 33, No. 9, 09.1994, p. 2215-2219.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Hydrolysis of methyl acetate and sucrose in SO3H-group-containing grafted polymer chains prepared by radiation-induced graft polymerization
AU - Mizota, Tomotoshi
AU - Tsuneda, Satoshi
AU - Saito, Kyoichi
AU - Sugo, Takanobu
PY - 1994/9
Y1 - 1994/9
N2 - The sulfonic acid (SO3H) group was attached to polyethylene by radiation-induced graft polymerization of sodium p-styrenesulfonate and compared with the SO3H group introduced into the polystyrene chain cross-linked with divinylbenzene. The catalytic activities of the SO3H group were measured in a batch mode for the hydrolysis of methyl acetate and sucrose. The temperature dependence of the reaction rate constants for the hydrolysis was determined. For the hydrolysis of methyl acetate, the SO3H group anchored to the grafted polymer chain had the same activity as the SO3H group introduced into the cross-linked polymer chain. On the other hand, the graft-type acid catalyst had about 10 times the hydrolytic activity for sucrose as the cross-linked acid catalyst.
AB - The sulfonic acid (SO3H) group was attached to polyethylene by radiation-induced graft polymerization of sodium p-styrenesulfonate and compared with the SO3H group introduced into the polystyrene chain cross-linked with divinylbenzene. The catalytic activities of the SO3H group were measured in a batch mode for the hydrolysis of methyl acetate and sucrose. The temperature dependence of the reaction rate constants for the hydrolysis was determined. For the hydrolysis of methyl acetate, the SO3H group anchored to the grafted polymer chain had the same activity as the SO3H group introduced into the cross-linked polymer chain. On the other hand, the graft-type acid catalyst had about 10 times the hydrolytic activity for sucrose as the cross-linked acid catalyst.
UR - http://www.scopus.com/inward/record.url?scp=0028495693&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0028495693&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0028495693
VL - 33
SP - 2215
EP - 2219
JO - Industrial & Engineering Chemistry Product Research and Development
JF - Industrial & Engineering Chemistry Product Research and Development
SN - 0888-5885
IS - 9
ER -