Hydrosilylation in the 2D interlayer space between inorganic layers: Reaction between immobilized C=C groups on the interlayer surface of layered perovskite HLaNb2O7·x H2O and chlorohydrosilanes

Satoru Yoshioka, Yosuke Takeda, Yuko Uchimaru, Yoshiyuki Sugahara

    Research output: Contribution to journalArticle

    16 Citations (Scopus)

    Abstract

    The C=C bonds immobilized in the interlayer space of layered perovskite, HLaNb2O7·xH2O, have undergone hydrosilylation reactions with chlorohydrosilanes. The C-C bonds are immobilized by the reaction between an n-propoxyl derivative of HLaNb2O7·xH2O and 4-penten-1-ol to form a CH2=CH(CH2)3 O- derivative of HLaNb2O7·xH2O, and a corresponding increase in the interlayer distance from 1.54 to 1.85 nm is observed. The CH2=CH(CH2)3 O- derivative is further treated with dichloromethylsilane or trichlorosilane, and the interlayer distance increases to 2.41 (dichloromethylsilane) or 2.07 (trichlorosilane) nm. Solid-state 13C-CP/MAS-NMR spectroscopy and infra-red (IR) spectroscopy reveal that the C-C groups disappear after the treatment with dichloromethylsilane or trichlorosilane, and 13C-NMR signals assignable to the hydrosilylated products are clearly observed. Besides hydrosilylation reactions, siloxane formation involving hydrolysis of the Si-Cl groups also proceeds. The structure of the perovskite-like slabs in HLaNb2O7·xH 2O is preserved throughout the process, indicating the successful modification of immobilized C-C groups via hydrosilylation with no structural change in the inorganic host layers.

    Original languageEnglish
    Pages (from-to)145-150
    Number of pages6
    JournalJournal of Organometallic Chemistry
    Volume686
    Issue number1-2
    DOIs
    Publication statusPublished - 2003 Dec 1

      Fingerprint

    Keywords

    • Chlorosilane
    • Dion-Jacobson phase
    • Grafting reaction
    • Hydrosilylation
    • Interlayer surface modification
    • Layered perovskite

    ASJC Scopus subject areas

    • Biochemistry
    • Inorganic Chemistry
    • Organic Chemistry
    • Physical and Theoretical Chemistry
    • Materials Chemistry

    Cite this