Identification and quantification of phenol-type antioxidants in low-density polyethylene by broadband far-infrared spectroscopy

Takaaki Ogishima, Chiaki Kuroda, Naoshi Hirai, Yoshimichi Ohki

Research output: Contribution to journal › Article

Abstract

Three kinds of phenol-type antioxidants, BHT, Irganox 1010, and Irganox 1330, were added to sheets of low density polyethylene (LDPE) and their absorption spectra were measured at terahertz and far-infrared frequencies. As a result, absorption with various peaks characteristic to each antioxidant appears. Most of these peaks increase monotonically with an increase in content of antioxidant, by which we can identify and quantify each antioxidant added in LDPE. In addition, by applying a partial-least squares regression method to the whole spectrum, the quantification of antioxidant can be improved.

Original languageEnglish
Pages (from-to)10-18
Number of pages9
JournalPolymer Testing
Volume76
DOIs
Publication statusPublished - 2019 Jul 1

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Low density polyethylenes
Polyethylene
Phenol
Antioxidants
Phenols
Infrared spectroscopy
Butylated Hydroxytoluene
Absorption spectra
Infrared radiation

Keywords

  • Antioxidant
  • Chemometrics
  • Insulating polymer
  • Quantification
  • Spectroscopy
  • Terahertz wave

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics

Cite this

Identification and quantification of phenol-type antioxidants in low-density polyethylene by broadband far-infrared spectroscopy. / Ogishima, Takaaki; Kuroda, Chiaki; Hirai, Naoshi; Ohki, Yoshimichi.

In: Polymer Testing, Vol. 76, 01.07.2019, p. 10-18.

Research output: Contribution to journal › Article

Ogishima, T, Kuroda, C, Hirai, N & Ohki, Y 2019, 'Identification and quantification of phenol-type antioxidants in low-density polyethylene by broadband far-infrared spectroscopy' Polymer Testing, vol. 76, pp. 10-18. https://doi.org/10.1016/j.polymertesting.2019.02.019
Ogishima T, Kuroda C, Hirai N, Ohki Y. Identification and quantification of phenol-type antioxidants in low-density polyethylene by broadband far-infrared spectroscopy. Polymer Testing. 2019 Jul 1;76:10-18. https://doi.org/10.1016/j.polymertesting.2019.02.019
Ogishima, Takaaki ; Kuroda, Chiaki ; Hirai, Naoshi ; Ohki, Yoshimichi. / Identification and quantification of phenol-type antioxidants in low-density polyethylene by broadband far-infrared spectroscopy. In: Polymer Testing. 2019 ; Vol. 76. pp. 10-18.
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