Impact of carbon segregant on microstructure and magnetic properties of FePt-C nanogranular films on MgO (001) substrate

J. Wang*, H. Sepehri-Amin, H. Tajiri, T. Nakamura, K. Masuda, Y. K. Takahashi, T. Ina, T. Uruga, I. Suzuki, Y. Miura, K. Hono

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

Carbon is the essential segregant to achieve the nanogranular structure of FePt-based heat-assisted magnetic recording media. However, a fundamental understanding of its effect on the microstructure and magnetic properties of the medium is yet to be elucidated. Here, a systematic investigation of FePt-C nanogranular films deposited on the single-crystalline MgO substrate with various C concentrations was performed. While the averaged FePt grain size can be successfully reduced to 5.8 nm, introducing excess C significantly degrades the degree of L1 0 ordering, the magnetic anisotropy, and the effective total magnetic moments of FePt films. Such degradation is mainly due to the finite size effects. Besides, the possible contribution form the dissolution of C atoms in the interstitial sites of the FePt lattice for the resulting magnetic properties was also studied via the first-principles calculations. More interestingly, fully in-plane c-axis-oriented FePt grains were observed even for growth on the MgO (001) substrate with a C concentration beyond 34.6 vol.%. Their formation is attributed to the reduced epitaxial strain energy due to the suppressed contact area at the FePt/MgO interface with excess C. Such grains were then identified as the main source of the in-plane component of the medium through micromagnetic simulation.

Original languageEnglish
Pages (from-to)413-423
Number of pages11
JournalActa Materialia
Volume166
DOIs
Publication statusPublished - 2019 Mar
Externally publishedYes

Keywords

  • Carbon
  • FePt
  • First-principles calculations
  • In-plane component
  • XMCD

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Polymers and Plastics
  • Metals and Alloys

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