In Situ Attenuated Total Reflection Fourier Transform Infrared Spectroscopy Studies of the Polyethylene Oxide/LiClO4-Metallic Lithium Interface

Toshihiro Ichino, Boris D. Cahan, Daniel Alberto Scherson

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The reactivity of polyethylene oxide/LiCI04 solid polymer electrolyte with metallic lithium has been investigated using attenuated total reflection Fourier transform infrared spectroscopy as an in situ probe of the vibrational properties of the interface. The results obtained have indicated that metallic lithium electrodeposited in situ reacts with PEO, leading to an irreversible cleavage of the ether functionality to generate the corresponding alkoxide as a product. This was evidenced by the appearance of a well-defined (ether-related) peak at 1110 cm-1, as well as a rather broad and not as well-defined peak of opposite polarity at 1200 cm-1. Also found in the spectra was a feature at 1090 cm-1 ascribed to perchlorate ions which migrate into and out of the near-surface region to preserve electroneutrality.

Original languageEnglish
Pages (from-to)L59-L61
JournalJournal of the Electrochemical Society
Volume138
Issue number11
DOIs
Publication statusPublished - 1991 Jan 1
Externally publishedYes

Fingerprint

Polyethylene oxides
Lithium
Ether
Fourier transform infrared spectroscopy
polyethylenes
Ethers
ethers
lithium
infrared spectroscopy
oxides
alkoxides
perchlorates
Electrolytes
cleavage
polarity
Polymers
reactivity
electrolytes
probes
Ions

ASJC Scopus subject areas

  • Electrochemistry
  • Condensed Matter Physics
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

Cite this

In Situ Attenuated Total Reflection Fourier Transform Infrared Spectroscopy Studies of the Polyethylene Oxide/LiClO4-Metallic Lithium Interface. / Ichino, Toshihiro; Cahan, Boris D.; Scherson, Daniel Alberto.

In: Journal of the Electrochemical Society, Vol. 138, No. 11, 01.01.1991, p. L59-L61.

Research output: Contribution to journalArticle

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