In Situ, Time-Resolved Raman Spectromicrotopography of an Operating Lithium-Ion Battery

Yu Luo, Wen Bin Cai, Xue Kun Xing, Daniel Alberto Scherson

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

A Raman microscope has been coupled to a sealed optical chamber mounted on a two-dimensional linear translator to allow in situ acquisition of space-, and time-resolved spectra from a sharply defined edge of thin operating graphite/LiCoO2 Li-ion battery exposing the anode (A), separator (S), and cathode (C), during charge and discharge along an axis normal to the layered A!S!C plane. Clear evidence was obtained for changes in the amount of Li+ within particles of graphite, and, to a lesser extent, of LiCoO2, during battery discharge both as a function of position and time. Such time-resolved Raman spectromicrotopography measurements can provide means of assessing the validity of theoretical models aimed at simulating the flow of Li+ within Li+-batteries under operating conditions.

Original languageEnglish
JournalElectrochemical and Solid-State Letters
Volume7
Issue number1
DOIs
Publication statusPublished - 2004 Feb 9
Externally publishedYes

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electric batteries
lithium
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Separators
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Anodes
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Microscopes
Cathodes
separators
acquisition
anodes
chambers
cathodes
microscopes
Lithium-ion batteries

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Materials Science(all)
  • Physical and Theoretical Chemistry
  • Electrochemistry
  • Electrical and Electronic Engineering

Cite this

In Situ, Time-Resolved Raman Spectromicrotopography of an Operating Lithium-Ion Battery. / Luo, Yu; Cai, Wen Bin; Xing, Xue Kun; Scherson, Daniel Alberto.

In: Electrochemical and Solid-State Letters, Vol. 7, No. 1, 09.02.2004.

Research output: Contribution to journalArticle

Luo, Yu ; Cai, Wen Bin ; Xing, Xue Kun ; Scherson, Daniel Alberto. / In Situ, Time-Resolved Raman Spectromicrotopography of an Operating Lithium-Ion Battery. In: Electrochemical and Solid-State Letters. 2004 ; Vol. 7, No. 1.
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