Influence of nano-particle agglomeration on the catalytic properties of MFI zeolite

S. Inagaki, I. Matsunaga, E. Kikuchi, Masahiko Matsukata

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    1 Citation (Scopus)

    Abstract

    Microstructures of spherical and coffin-shaped MFI zeolite and its effect on the catalytic activity for cumene cracking were studied. While spherical MFI was composed of nanoparticles, coffin-shaped one has a layered structure where nanoparticles with ~ 30 nm in size were accumulated on the dense core. Both the thickness of nano-particles layer and mesopore volume linearly correlated with the activity for cumene cracking, suggesting that the mesopores in MFI particles formed during nanoparticles agglomeration, and that the reaction rate of cumene cracking was significantly affected by the diffusion of cumene molecule in the nanoparticles agglomerating layer. This is an abstract of a paper presented at the 13th International Zeolite Conference (Montpellier, France 7/8-13/2001).

    Original languageEnglish
    Title of host publicationZeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001
    PublisherElsevier Inc.
    Pages332
    Number of pages1
    Volume135
    ISBN (Print)9780444502384
    DOIs
    Publication statusPublished - 2001
    EventZeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001 - Montpellier, France
    Duration: 2001 Jun 82001 Jun 13

    Other

    OtherZeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001
    CountryFrance
    CityMontpellier
    Period01/6/801/6/13

    Fingerprint

    Zeolites
    agglomeration
    Agglomeration
    Nanoparticles
    nanoparticles
    France
    Reaction rates
    catalytic activity
    Catalyst activity
    reaction kinetics
    microstructure
    Microstructure
    Molecules
    cumene
    molecules

    ASJC Scopus subject areas

    • Catalysis
    • Condensed Matter Physics
    • Surfaces, Coatings and Films
    • Physical and Theoretical Chemistry
    • Materials Chemistry

    Cite this

    Inagaki, S., Matsunaga, I., Kikuchi, E., & Matsukata, M. (2001). Influence of nano-particle agglomeration on the catalytic properties of MFI zeolite. In Zeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001 (Vol. 135, pp. 332). Elsevier Inc.. https://doi.org/10.1016/S0167-2991(01)81765-1

    Influence of nano-particle agglomeration on the catalytic properties of MFI zeolite. / Inagaki, S.; Matsunaga, I.; Kikuchi, E.; Matsukata, Masahiko.

    Zeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001. Vol. 135 Elsevier Inc., 2001. p. 332.

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Inagaki, S, Matsunaga, I, Kikuchi, E & Matsukata, M 2001, Influence of nano-particle agglomeration on the catalytic properties of MFI zeolite. in Zeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001. vol. 135, Elsevier Inc., pp. 332, Zeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001, Montpellier, France, 01/6/8. https://doi.org/10.1016/S0167-2991(01)81765-1
    Inagaki S, Matsunaga I, Kikuchi E, Matsukata M. Influence of nano-particle agglomeration on the catalytic properties of MFI zeolite. In Zeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001. Vol. 135. Elsevier Inc. 2001. p. 332 https://doi.org/10.1016/S0167-2991(01)81765-1
    Inagaki, S. ; Matsunaga, I. ; Kikuchi, E. ; Matsukata, Masahiko. / Influence of nano-particle agglomeration on the catalytic properties of MFI zeolite. Zeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001. Vol. 135 Elsevier Inc., 2001. pp. 332
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    abstract = "Microstructures of spherical and coffin-shaped MFI zeolite and its effect on the catalytic activity for cumene cracking were studied. While spherical MFI was composed of nanoparticles, coffin-shaped one has a layered structure where nanoparticles with ~ 30 nm in size were accumulated on the dense core. Both the thickness of nano-particles layer and mesopore volume linearly correlated with the activity for cumene cracking, suggesting that the mesopores in MFI particles formed during nanoparticles agglomeration, and that the reaction rate of cumene cracking was significantly affected by the diffusion of cumene molecule in the nanoparticles agglomerating layer. This is an abstract of a paper presented at the 13th International Zeolite Conference (Montpellier, France 7/8-13/2001).",
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