Infrared identification of the Criegee intermediates syn- and anti-CH3CHOO, and their distinct conformation-dependent reactivity

Hui Yu Lin, Yu Hsuan Huang, Xiaohong Wang, Joel M. Bowman, Yoshifumi Nishimura, Henryk A. Witek, Yuan Pern Lee

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

The Criegee intermediates are carbonyl oxides that play critical roles in ozonolysis of alkenes in the atmosphere. So far, the mid-infrared spectrum of only the simplest Criegee intermediate CH2OO has been reported. Methyl substitution of CH2OO produces two conformers of CH3CHOO and consequently complicates the infrared spectrum. Here we report the transient infrared spectrum of syn- and anti-CH3CHOO, produced from CH3CHI + O2 in a flow reactor, using a step-scan Fourier-transform spectrometer. Guided and supported by high-level full-dimensional quantum calculations, rotational contours of the four observed bands are simulated successfully and provide definitive identification of both conformers. Furthermore, anti-CH3CHOO shows a reactivity greater than syn-CH3CHOO towards NO/NO2; at the later period of reaction, the spectrum can be simulated with only syn-CH3CHOO. Without NO/NO2, anti-CH3CHOO also decays much faster than syn-CH3CHOO. The direct infrared detection of syn- and anti-CH3CHOO should prove useful for field measurements and laboratory investigations of the Criegee mechanism.

Original languageEnglish
Article number7012
JournalNature Communications
Volume6
DOIs
Publication statusPublished - 2015 May 11
Externally publishedYes

Fingerprint

Alkenes
Fourier Analysis
Atmosphere
Oxides
Conformations
infrared spectra
reactivity
Infrared radiation
alkenes
reactors
spectrometers
substitutes
Spectrometers
atmospheres
Fourier transforms
Substitution reactions
oxides
decay

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)
  • Chemistry(all)
  • Physics and Astronomy(all)

Cite this

Infrared identification of the Criegee intermediates syn- and anti-CH3CHOO, and their distinct conformation-dependent reactivity. / Lin, Hui Yu; Huang, Yu Hsuan; Wang, Xiaohong; Bowman, Joel M.; Nishimura, Yoshifumi; Witek, Henryk A.; Lee, Yuan Pern.

In: Nature Communications, Vol. 6, 7012, 11.05.2015.

Research output: Contribution to journalArticle

Lin, Hui Yu ; Huang, Yu Hsuan ; Wang, Xiaohong ; Bowman, Joel M. ; Nishimura, Yoshifumi ; Witek, Henryk A. ; Lee, Yuan Pern. / Infrared identification of the Criegee intermediates syn- and anti-CH3CHOO, and their distinct conformation-dependent reactivity. In: Nature Communications. 2015 ; Vol. 6.
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