Infrared spectroscopic study on electric-field-induced dynamics of polymer chains in a ferroelectric melt-quenched cold-drawn film of nylon-12

Hayato Isoda, Yukio Furukawa

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    We studied the intensity changes of the infrared bands of a ferroelectric melt-quenched, cold-drawn film of nylon-12 as a function of an external cyclic stepwise electric field with the polarization perpendicular to the draw direction. The infrared bands assigned to the NH stretching and amide I modes exhibited butterfly-shaped hysteresis loops characteristic of ferroelectric materials, whereas the intensity changes of the infrared bands assigned to the CH2 antisymmetric and symmetric stretching modes were small and showed no butterfly-shaped hysteresis loops. These results indicate that only the amide groups were inverted under the external electric field. We proposed a molecular mechanism explaining the ferroelectric properties of nylon-12: The amide groups in the antiparallel β-sheet structure are inverted by the external electric field to form new hydrogen bonds, generating two stable states in a nearly double-minimum potential.

    Original languageEnglish
    Pages (from-to)30-37
    Number of pages8
    JournalVibrational Spectroscopy
    Volume84
    DOIs
    Publication statusPublished - 2016 May 1

    Fingerprint

    Amides
    Ferroelectric materials
    Polymers
    Electric fields
    Hysteresis loops
    Infrared radiation
    Stretching
    Hydrogen bonds
    Polarization
    nylon 12
    Direction compound

    Keywords

    • Ferroelectricity
    • Infrared spectroscopy
    • Nylon-12
    • Polarized IR measurements
    • Polymers

    ASJC Scopus subject areas

    • Spectroscopy

    Cite this

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    abstract = "We studied the intensity changes of the infrared bands of a ferroelectric melt-quenched, cold-drawn film of nylon-12 as a function of an external cyclic stepwise electric field with the polarization perpendicular to the draw direction. The infrared bands assigned to the NH stretching and amide I modes exhibited butterfly-shaped hysteresis loops characteristic of ferroelectric materials, whereas the intensity changes of the infrared bands assigned to the CH2 antisymmetric and symmetric stretching modes were small and showed no butterfly-shaped hysteresis loops. These results indicate that only the amide groups were inverted under the external electric field. We proposed a molecular mechanism explaining the ferroelectric properties of nylon-12: The amide groups in the antiparallel β-sheet structure are inverted by the external electric field to form new hydrogen bonds, generating two stable states in a nearly double-minimum potential.",
    keywords = "Ferroelectricity, Infrared spectroscopy, Nylon-12, Polarized IR measurements, Polymers",
    author = "Hayato Isoda and Yukio Furukawa",
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    T1 - Infrared spectroscopic study on electric-field-induced dynamics of polymer chains in a ferroelectric melt-quenched cold-drawn film of nylon-12

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    AU - Furukawa, Yukio

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    N2 - We studied the intensity changes of the infrared bands of a ferroelectric melt-quenched, cold-drawn film of nylon-12 as a function of an external cyclic stepwise electric field with the polarization perpendicular to the draw direction. The infrared bands assigned to the NH stretching and amide I modes exhibited butterfly-shaped hysteresis loops characteristic of ferroelectric materials, whereas the intensity changes of the infrared bands assigned to the CH2 antisymmetric and symmetric stretching modes were small and showed no butterfly-shaped hysteresis loops. These results indicate that only the amide groups were inverted under the external electric field. We proposed a molecular mechanism explaining the ferroelectric properties of nylon-12: The amide groups in the antiparallel β-sheet structure are inverted by the external electric field to form new hydrogen bonds, generating two stable states in a nearly double-minimum potential.

    AB - We studied the intensity changes of the infrared bands of a ferroelectric melt-quenched, cold-drawn film of nylon-12 as a function of an external cyclic stepwise electric field with the polarization perpendicular to the draw direction. The infrared bands assigned to the NH stretching and amide I modes exhibited butterfly-shaped hysteresis loops characteristic of ferroelectric materials, whereas the intensity changes of the infrared bands assigned to the CH2 antisymmetric and symmetric stretching modes were small and showed no butterfly-shaped hysteresis loops. These results indicate that only the amide groups were inverted under the external electric field. We proposed a molecular mechanism explaining the ferroelectric properties of nylon-12: The amide groups in the antiparallel β-sheet structure are inverted by the external electric field to form new hydrogen bonds, generating two stable states in a nearly double-minimum potential.

    KW - Ferroelectricity

    KW - Infrared spectroscopy

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    KW - Polarized IR measurements

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