Inorganicorganic hybrid photomechanical crystals of azobenzene-modified polyhedral oligomeric silsesquioxane (POSS)

Ryota Kajiya; Hiroaki Wada; Kazuyuki Kuroda; Atsushi Shimojima

doi:10.1246/cl.190926

Inorganicorganic hybrid photomechanical crystals of azobenzene-modified polyhedral oligomeric silsesquioxane (POSS)

Ryota Kajiya, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima

School of Advanced Science and Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

A new class of inorganicorganic hybrid photomechanical material has been created by mono-substitution of polyhedral oligomeric silsesquioxane (POSS) with an azobenzene group via amide bond formation. This compound formed needle-like molecular crystals showing reversible photoinduced bending motions. This finding provides a new design concept of photomechanical materials for various applications.

Original language	English
Pages (from-to)	327-329
Number of pages	3
Journal	Chemistry Letters
Volume	49
Issue number	3
DOIs	https://doi.org/10.1246/cl.190926
Publication status	Published - 2020

Keywords

Azobenzene
Photomechanical material
Polyhedral oligomeric silsesquioxane (POSS)

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.190926

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abstract = "A new class of inorganicorganic hybrid photomechanical material has been created by mono-substitution of polyhedral oligomeric silsesquioxane (POSS) with an azobenzene group via amide bond formation. This compound formed needle-like molecular crystals showing reversible photoinduced bending motions. This finding provides a new design concept of photomechanical materials for various applications.",

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AU - Kajiya, Ryota

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AU - Kuroda, Kazuyuki

AU - Shimojima, Atsushi

PY - 2020

Y1 - 2020

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KW - Azobenzene

KW - Photomechanical material

KW - Polyhedral oligomeric silsesquioxane (POSS)

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