Interaction between polynuclear aromatic hydrocarbons and sodium ion in poly (oxyethylene)

Shinji Takeoka, Kohji Horiuchi, Eishun Tsuchida

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The ion-ion interaction of the ion pairs between radical anions of π-conjugative molecules (polynuclear aromatic hydrocarbons, AR) such as anthracene, phenanthrene or naphthalene, and sodium ion in CH3(OCH2CH2)xOCH3 was evaluated from ionic conductivity measurement. The rate of ion-dissociation increased as either the number of (oxyethylene) unit (x) or the electron affinity of AR increased. This indicates that the continuous (oxyethylene) units are more favorable for ion-dissociation and a molecule having higher ability to become a radical anion shows higher rate of dissociation.

Original languageEnglish
Pages (from-to)175-179
Number of pages5
JournalSolid State Ionics
Volume50
Issue number1-2
DOIs
Publication statusPublished - 1992 Jan

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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