Intercalation of n-Alkylamines into Perovskite-related Layered Niobic Acid HBiNb2O7·nH2O

Teruyuki Nakato, Masato Nakade, Kazuyuki Kuroda, Chuzo Kato

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

n-Alkylammonium-HxBiNb2O7 intercalation compounds were synthesized by the reaction of perovskite-related layered oxide HBiNb2O7·nH2O with n-alkylamines. HBiNb2O7·nH2O was not completely converted to the intercalation compounds except for the methylammonium-intercalate. The intercalating capability of HBiNb2O7·nH2O was much lower than those of other previously reported perovskite-related layered niobates such as HCa2Nb3O10. The poor reactivity was assumed to be related to unusual irreversible dehydrating behavior of HBiNb2O7·nH2O. On the other hand, the interlayer structure was similar to that of the n-alkylammonium-HxCa2Nb3O10 intercalates in contrast to the difference in the reactivity.

Original languageEnglish
Pages (from-to)285-290
Number of pages6
JournalStudies in Surface Science and Catalysis
Volume90
Issue numberC
DOIs
Publication statusPublished - 1994 Jan 1

ASJC Scopus subject areas

  • Catalysis
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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