Intercalation of tris(2,2′-bipyridine)ruthenium(II) into magadiite

M. Ogawa, N. Maeda

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Intercalation of the tris(2,2′-bipyridine)ruthenium(II) complex cation into a layered silicate (magadiite; the ideal formula for which is Na2Si14O29·nH2O) was investigated. Since the complex cation did not intercalate by a direct ion exchange reaction with the interlayer Na ions in an aqueous medium, dodecyltrimethylammonium exchanged magadiite was used as a precursor. Depending on the loading of the complex cations and the solvents employed for the reactions, two types of tris(2,2′-bipyridine)ruthenium(II)-magadiite intercalation compounds formed. One has a basal spacing of ∼2.9 nm due to a large amount of the dodecyltrimethylammonium ions which remained in the interlayer space of magadiite and coexisted with the intercalated tris(2,2′-bipyridine)ruthenium(II) complex cations. The other has a basal spacing of ∼2.0 nm because the intercalated tris(2,2′-bipyridine)ruthenium(II) complex ions form a monolayer in the interlayer space of magadiite.

Original languageEnglish
Pages (from-to)643-650
Number of pages8
JournalClay Minerals
Volume33
Issue number4
Publication statusPublished - 1998 Dec

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magadiite
ruthenium
Ruthenium
Intercalation
Cations
cation
Ions
ion
spacing
Silicates
Intercalation compounds
Monolayers
Ion exchange
ion exchange
silicate

ASJC Scopus subject areas

  • Geochemistry and Petrology

Cite this

Intercalation of tris(2,2′-bipyridine)ruthenium(II) into magadiite. / Ogawa, M.; Maeda, N.

In: Clay Minerals, Vol. 33, No. 4, 12.1998, p. 643-650.

Research output: Contribution to journalArticle

Ogawa, M & Maeda, N 1998, 'Intercalation of tris(2,2′-bipyridine)ruthenium(II) into magadiite', Clay Minerals, vol. 33, no. 4, pp. 643-650.
Ogawa, M. ; Maeda, N. / Intercalation of tris(2,2′-bipyridine)ruthenium(II) into magadiite. In: Clay Minerals. 1998 ; Vol. 33, No. 4. pp. 643-650.
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