Interfacial phenomena of radiation-induced and photo-induced

Yoshio Honjo, Masahiro Furuya, Tomoji Takamasa, Koji Okamoto

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

When a metal oxide is irradiated by gamma rays, the irradiated surface becomes hydrophilic. This surface phenomenon is called as radiation induced surface activation (RISA). In order to investigate radiation-induced and photo- induced hydrophilicity, the contact angles of water droplets on a titanium dioxide surface were measured in terms of irradiation intensity and time for gamma rays of cobalt-60 and for ultraviolet rays. Reciprocals of the contact angles increased in proportion to irradiation time before the contact angles reached their super-hydrophilicity state. The reciprocals of contact angles correlate well with integrated intensity by a straight line, regardless of the irradiation intensity and time. Radiation induced and photo-induced hydrophilicity phenomena are identical to each other in this regard. In addition, an effect of ambient gas was investigated. In pure argon gas, the contact angle remains the same against the irradiation time. This clearly shows that a certain humidity in ambicnt gas is required to take thc placc of RISA hydrophilicity. A single crystal titanium dioxide (100) surface was analyzed by X-ray photoelectron spectrometry (XPS). After irradiation with gamma rays, a peak was found in the 0 Is spectrum, indicating the adsorption of dissociative water to a surface 5-fold coordinate titanium site, and the formation of a surface hydroxyl group. We conclude that the RISA hydrophilicity is caused by chemisorption of the hydroxyl group on the surface.

Original languageEnglish
Title of host publication2008 Proceedings of the 16th International Conference on Nuclear Engineering, ICONE16
Pages353-360
Number of pages8
DOIs
Publication statusPublished - 2008 Dec 1
Externally publishedYes
Event16th International Conference on Nuclear Engineering, ICONE16 2008 - Orlando, FL, United States
Duration: 2008 May 112008 May 15

Publication series

NameInternational Conference on Nuclear Engineering, Proceedings, ICONE
Volume3

Conference

Conference16th International Conference on Nuclear Engineering, ICONE16 2008
CountryUnited States
CityOrlando, FL
Period08/5/1108/5/15

ASJC Scopus subject areas

  • Nuclear Energy and Engineering

Fingerprint Dive into the research topics of 'Interfacial phenomena of radiation-induced and photo-induced'. Together they form a unique fingerprint.

Cite this