Investigation of physical and chemical characteristics of radioactive aerosols emitted from reactor unit 1 by fukushima daiichi nuclear power plant accident

Seika Onozaki, Yoshinari Abe, Izumi Nakai, Kouji Adachi, Yasuhito Igarashi, Yasuji Oura, Mitsuru Ebihara, Takafumi Miyasaka, Hisashi Nakamura, Keisuke Sueki, Haruo Tsuruta, Yuichi Moriguchi

Research output: Contribution to journalArticle

Abstract

Three radioactive microparticles were separated from particles on filter tape samples collected hourly at a suspended particulate matter (SPM) monitoring site located at ~25 km north of the Fukushima Daiichi Nuclear Power Plant (FDNPP), after the hydrogen explosion of reactor 1 on 12th March 2011. The 134Cs/137Cs radioactivity ratios of the three radioactive aerosol particles showed that they were derived from the FDNPP reactor 1, rather than reactors 2 or 3. The physical characteristics of these particles with < 10 µm in diameter and nonuniform shape are clearly different from those of radioactive particles generated by the hydrogen explosion of the FDNPP reactor 1. A significant amount of Cl was detected by energy dispaersive X-ray spectrometery. Synchrosron radiation microbeam (SR-µ-) X-ray fluoresence (XRF) analysis showed that these particles contain a series of heavy elements related to the nuclear fules and their fission products with a non-homogeneous distribution within the particles. In addition, the SR-µ-XRF identified trace amounts of Br in these particles; the element has firstly been found in radioactive particles derived by the FDNPP accident. In contrast to the hydrogen explosion-generated radioactive particles containing Sr and Ba, both of which are easily volatile under a reduction atmosphere, these elements were not rich in the particles found in this study. By the SR-µ-X-ray absorption near edge structure analysis and SR-µ-X-ray powder diffraction, it was found that these particles consist of an amorphous (or low crystalline) matrix containing metal elements with chemical states in a comparatively high state of oxidation or chloride. Based on these physical and chemical characteristics and a trajectory analysis of air parcels that passed over the SPM monitoring site, we concluded that these radioactive particles were generated and emitted into the atomosphere at the time of seawater injection for cooling the reactor after the hydrogen explosion.

Original languageEnglish
Pages (from-to)757-768
Number of pages12
JournalBUNSEKI KAGAKU
Volume68
Issue number10
DOIs
Publication statusPublished - 2019

Keywords

  • Aerosol particle
  • Fukushima daiichi nuclear power plant accident
  • Radioactive material
  • Synchrotron radiation X-ray analysis

ASJC Scopus subject areas

  • Analytical Chemistry

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  • Cite this

    Onozaki, S., Abe, Y., Nakai, I., Adachi, K., Igarashi, Y., Oura, Y., Ebihara, M., Miyasaka, T., Nakamura, H., Sueki, K., Tsuruta, H., & Moriguchi, Y. (2019). Investigation of physical and chemical characteristics of radioactive aerosols emitted from reactor unit 1 by fukushima daiichi nuclear power plant accident. BUNSEKI KAGAKU, 68(10), 757-768. https://doi.org/10.2116/bunsekikagaku.68.757