Ion-exchange reactions of a layered aluminophosphate, [AlPO 4(OH)](C6H5C2H4NH 3)

Masato Mesaki, Fumiaki Tando, Seiichi Tahara, Yoshiyuki Sugahara

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    Reactions between a layered aluminophosphate [AlPO4(OH)](C 6H5C2H4NH3) and an nalkylammonium ion [n-propylammonium (C3), n-butylammonium (C4) or n-hexylammonium ion (C6)] were examined. Upon reactions, the X-ray diffraction (XRD) patterns of the products showed changes in the interlayer distance from 1.97 nm to 1.66 nm (AlPO-C3), 1.86 nm (AlPO-C4), and 2.26 nm (AlPO-C6), and the interlayer distance thus increased linearly with increases in the length of the n-alkyl chains. Solid-state 13C nuclear magnetic resonance spectroscopy with cross polarization and magic angle spinning techniques ( 13C CP/MAS NMR) and infrared adsorption (IR) spectroscopy showed that C6H5C2H4NH3 + ions were eliminated and n-CnH2n+1NH3 + ions were introduced. Scanning electron microscopy (SEM) images showed, moreover, that the platy morphology of [AlPO4(OH)](C 6H5C2H4NH3) was maintained upon reactions. These results demonstrate that [AlPO 4(OH)](C6H5C2H4NH 3) underwent ion-exchange reactions with n-alkylammonium ions.

    Original languageEnglish
    Title of host publicationMaterials Research Society Symposium Proceedings
    Pages143-148
    Number of pages6
    Volume1148
    Publication statusPublished - 2008
    Event2008 MRS Fall Meeting - Boston, MA
    Duration: 2008 Dec 12008 Dec 5

    Other

    Other2008 MRS Fall Meeting
    CityBoston, MA
    Period08/12/108/12/5

    Fingerprint

    Ion exchange
    Ions
    ions
    interlayers
    Magic angle spinning
    nuclear magnetic resonance
    cross polarization
    Diffraction patterns
    Nuclear magnetic resonance spectroscopy
    magnetic resonance spectroscopy
    metal spinning
    Nuclear magnetic resonance
    Spectroscopy
    Polarization
    Infrared radiation
    diffraction patterns
    Adsorption
    X ray diffraction
    Scanning electron microscopy
    solid state

    ASJC Scopus subject areas

    • Materials Science(all)
    • Condensed Matter Physics
    • Mechanical Engineering
    • Mechanics of Materials

    Cite this

    Mesaki, M., Tando, F., Tahara, S., & Sugahara, Y. (2008). Ion-exchange reactions of a layered aluminophosphate, [AlPO 4(OH)](C6H5C2H4NH 3). In Materials Research Society Symposium Proceedings (Vol. 1148, pp. 143-148)

    Ion-exchange reactions of a layered aluminophosphate, [AlPO 4(OH)](C6H5C2H4NH 3). / Mesaki, Masato; Tando, Fumiaki; Tahara, Seiichi; Sugahara, Yoshiyuki.

    Materials Research Society Symposium Proceedings. Vol. 1148 2008. p. 143-148.

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Mesaki, M, Tando, F, Tahara, S & Sugahara, Y 2008, Ion-exchange reactions of a layered aluminophosphate, [AlPO 4(OH)](C6H5C2H4NH 3). in Materials Research Society Symposium Proceedings. vol. 1148, pp. 143-148, 2008 MRS Fall Meeting, Boston, MA, 08/12/1.
    Mesaki M, Tando F, Tahara S, Sugahara Y. Ion-exchange reactions of a layered aluminophosphate, [AlPO 4(OH)](C6H5C2H4NH 3). In Materials Research Society Symposium Proceedings. Vol. 1148. 2008. p. 143-148
    Mesaki, Masato ; Tando, Fumiaki ; Tahara, Seiichi ; Sugahara, Yoshiyuki. / Ion-exchange reactions of a layered aluminophosphate, [AlPO 4(OH)](C6H5C2H4NH 3). Materials Research Society Symposium Proceedings. Vol. 1148 2008. pp. 143-148
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    AU - Sugahara, Yoshiyuki

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