Ir-catalyzed almost perfect enantioselective synthesis of helical polyaryls based on an axially-chiral sequence

Takanori Shibata, Kyoji Tsuchikama

    Research output: Contribution to journalArticle

    45 Citations (Scopus)

    Abstract

    Ir-catalyzed enantioselective [2 + 2 + 2] cycloaddition of tetraynes or an octayne with monoalkynes proceeded to give helically-chiral quinquearyl and noviaryl compounds, which respectively have four and eight consecutive axial chiralities, in an almost enantiomerically pure form.

    Original languageEnglish
    Pages (from-to)6017-6019
    Number of pages3
    JournalChemical Communications
    Issue number48
    DOIs
    Publication statusPublished - 2005 Dec 28

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    Cycloaddition
    Chirality

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Ir-catalyzed almost perfect enantioselective synthesis of helical polyaryls based on an axially-chiral sequence. / Shibata, Takanori; Tsuchikama, Kyoji.

    In: Chemical Communications, No. 48, 28.12.2005, p. 6017-6019.

    Research output: Contribution to journalArticle

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