Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines

Shiguang Pan, Kohei Endo, Takanori Shibata

    Research output: Contribution to journalArticle

    62 Citations (Scopus)

    Abstract

    A cationic Ir(I)-C 3-TUNEPHOS complex catalyzed an intermolecular hydroamination of styrene derivatives with various heteroaromatic amines. The reaction gave Markovnikov products with perfect regioselectivity and good enantioselectivity under solvent-free conditions.

    Original languageEnglish
    Pages (from-to)780-783
    Number of pages4
    JournalOrganic Letters
    Volume14
    Issue number3
    DOIs
    Publication statusPublished - 2012 Feb 3

    Fingerprint

    Regioselectivity
    Styrene
    Enantioselectivity
    Alkenes
    styrenes
    alkenes
    Amines
    amines
    Derivatives
    products

    ASJC Scopus subject areas

    • Organic Chemistry
    • Physical and Theoretical Chemistry
    • Biochemistry

    Cite this

    Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines. / Pan, Shiguang; Endo, Kohei; Shibata, Takanori.

    In: Organic Letters, Vol. 14, No. 3, 03.02.2012, p. 780-783.

    Research output: Contribution to journalArticle

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