Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes

Takanori Shibata; Sho Kadowaki; Masaya Hirase; Kentaro Takagi

doi:10.1055/s-2003-37532

Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes

Takanori Shibata^*, Sho Kadowaki, Masaya Hirase, Kentaro Takagi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Abstract

Vaska's complex [IrCl(CO)(PPh₃)₂] efficiently catalyzes the intramolecular carbonylative [2+2+1] cycloaddition of allenynes. A dimethyl substituent on the allene terminus and a low partial pressure of carbon monoxide realize the selective engagement of the internal π-bond of allene.

Original language	English
Pages (from-to)	573-575
Number of pages	3
Journal	Synlett
Issue number	4
DOIs	https://doi.org/10.1055/s-2003-37532
Publication status	Published - 2003
Externally published	Yes

Keywords

Alkynes
Allenes
Carbonylations
Iridium
Pauson-Khand reaction

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-2003-37532

Cite this

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title = "Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes",

abstract = "Vaska's complex [IrCl(CO)(PPh3)2] efficiently catalyzes the intramolecular carbonylative [2+2+1] cycloaddition of allenynes. A dimethyl substituent on the allene terminus and a low partial pressure of carbon monoxide realize the selective engagement of the internal π-bond of allene.",

keywords = "Alkynes, Allenes, Carbonylations, Iridium, Pauson-Khand reaction",

author = "Takanori Shibata and Sho Kadowaki and Masaya Hirase and Kentaro Takagi",

year = "2003",

doi = "10.1055/s-2003-37532",

language = "English",

pages = "573--575",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "4",

}

TY - JOUR

T1 - Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes

AU - Shibata, Takanori

AU - Kadowaki, Sho

AU - Hirase, Masaya

AU - Takagi, Kentaro

PY - 2003

Y1 - 2003

N2 - Vaska's complex [IrCl(CO)(PPh3)2] efficiently catalyzes the intramolecular carbonylative [2+2+1] cycloaddition of allenynes. A dimethyl substituent on the allene terminus and a low partial pressure of carbon monoxide realize the selective engagement of the internal π-bond of allene.

AB - Vaska's complex [IrCl(CO)(PPh3)2] efficiently catalyzes the intramolecular carbonylative [2+2+1] cycloaddition of allenynes. A dimethyl substituent on the allene terminus and a low partial pressure of carbon monoxide realize the selective engagement of the internal π-bond of allene.

KW - Alkynes

KW - Allenes

KW - Carbonylations

KW - Iridium

KW - Pauson-Khand reaction

UR - http://www.scopus.com/inward/record.url?scp=0037237357&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037237357&partnerID=8YFLogxK

U2 - 10.1055/s-2003-37532

DO - 10.1055/s-2003-37532

M3 - Article

AN - SCOPUS:0037237357

SN - 0936-5214

SP - 573

EP - 575

JO - Synlett

JF - Synlett

IS - 4

ER -

Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes

Abstract

Keywords

ASJC Scopus subject areas

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