Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes

Takanori Shibata, Sho Kadowaki, Masaya Hirase, Kentaro Takagi

Research output: Contribution to journalArticle

52 Citations (Scopus)

Abstract

Vaska's complex [IrCl(CO)(PPh3)2] efficiently catalyzes the intramolecular carbonylative [2+2+1] cycloaddition of allenynes. A dimethyl substituent on the allene terminus and a low partial pressure of carbon monoxide realize the selective engagement of the internal π-bond of allene.

Original languageEnglish
Pages (from-to)573-575
Number of pages3
JournalSynlett
Issue number4
Publication statusPublished - 2003
Externally publishedYes

Fingerprint

Iridium
Carbon Monoxide
Cycloaddition
Partial pressure
propadiene

Keywords

  • Alkynes
  • Allenes
  • Carbonylations
  • Iridium
  • Pauson-Khand reaction

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Shibata, T., Kadowaki, S., Hirase, M., & Takagi, K. (2003). Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes. Synlett, (4), 573-575.

Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes. / Shibata, Takanori; Kadowaki, Sho; Hirase, Masaya; Takagi, Kentaro.

In: Synlett, No. 4, 2003, p. 573-575.

Research output: Contribution to journalArticle

Shibata, T, Kadowaki, S, Hirase, M & Takagi, K 2003, 'Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes', Synlett, no. 4, pp. 573-575.
Shibata T, Kadowaki S, Hirase M, Takagi K. Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes. Synlett. 2003;(4):573-575.
Shibata, Takanori ; Kadowaki, Sho ; Hirase, Masaya ; Takagi, Kentaro. / Iridium complex-catalyzed Pauson-Khand-type reaction of allenynes. In: Synlett. 2003 ; No. 4. pp. 573-575.
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