Ir(III)-Catalyzed room-temperature synthesis of multisubstituted benzofurans initiated by C-H activation of -aryloxy ketones

Takanori Shibata, Yu Ki Hashimoto, Maiko Otsuka, Kyoji Tsuchikama, Kohei Endo

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Cyclodehydration of various -aryloxy ketones proceeded to give various multisubstituted benzofurans by using an Ir(III) catalyst, which was prepared from [Cp IrCl AgSbF and Cu(OAc) The use of the cationic iridium complex with a carboxylate salt realized the efficient transformation at ambient temperature.

Original languageEnglish
Article numberU04111ST
Pages (from-to)2075-2079
Number of pages5
JournalSynlett
Issue number14
DOIs
Publication statusPublished - 2011 Aug 5

Keywords

  • C-H activation
  • benzofurans
  • cyclodehydration
  • iridium
  • room temperature

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Dive into the research topics of 'Ir(III)-Catalyzed room-temperature synthesis of multisubstituted benzofurans initiated by C-H activation of -aryloxy ketones'. Together they form a unique fingerprint.

  • Cite this