Kinetics of the reactions of ozone with 2,5-dimethylfuran and its atmospheric implications

Jun Matsumoto

doi:10.1246/cl.2011.582

Kinetics of the reactions of ozone with 2,5-dimethylfuran and its atmospheric implications

Jun Matsumoto^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

To determine the reaction rate coefficient of volatile organic compounds with ozone, the reduction of ozone through a flow-tube reactor was measured by a chemiluminescent detector. The validity of the method was confirmed by examination on isoprene. Consequently, the reaction rate coefficient of 2,5-dimethylfuran, DMF, with ozone was determined as (4.2 ± 0.9) × ^10-16 cm³ molecule^-1 s^-1 for the first time. It was suggested that ozonolysis can be important for the fate of DMF in the atmosphere.

Original language	English
Pages (from-to)	582-583
Number of pages	2
Journal	Chemistry Letters
Volume	40
Issue number	6
DOIs	https://doi.org/10.1246/cl.2011.582
Publication status	Published - 2011
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2011.582

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abstract = "To determine the reaction rate coefficient of volatile organic compounds with ozone, the reduction of ozone through a flow-tube reactor was measured by a chemiluminescent detector. The validity of the method was confirmed by examination on isoprene. Consequently, the reaction rate coefficient of 2,5-dimethylfuran, DMF, with ozone was determined as (4.2 ± 0.9) × 10-16 cm3 molecule-1 s-1 for the first time. It was suggested that ozonolysis can be important for the fate of DMF in the atmosphere.",

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AB - To determine the reaction rate coefficient of volatile organic compounds with ozone, the reduction of ozone through a flow-tube reactor was measured by a chemiluminescent detector. The validity of the method was confirmed by examination on isoprene. Consequently, the reaction rate coefficient of 2,5-dimethylfuran, DMF, with ozone was determined as (4.2 ± 0.9) × 10-16 cm3 molecule-1 s-1 for the first time. It was suggested that ozonolysis can be important for the fate of DMF in the atmosphere.

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Kinetics of the reactions of ozone with 2,5-dimethylfuran and its atmospheric implications

Abstract

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