Layered (1-x-y)LiNi1/2Mn1/2O2 · x Li[Li1/3Mn2/3] O2 · yLiCoO2 (0≤x = y≤0.3 and x + y = 0.5) cathode materials

Lianqi Zhang, Kazunori Takada, Narumi Ohta, Katsutoshi Fukuda, Minoru Osada, Lianzhou Wang, Takayoshi Sasaki, Mamoru Watanabe

Research output: Contribution to journalArticle

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Abstract

An exploration of new cathode materials along the two lines having the nominal compositions of (1 - x - y)LiNi1/2Mn1/2O 2 · x Li[Li1/3Mn2/3]O2 · yLiCoO2 (0 ≤ x = y ≤ 0.3 and x + y = 0.5) was performed in the phase diagram of LiNi1/2Mn1/2O 2-Li[Li1/3Mn2/3]O2-LiCoO 2 by a simple solid-state reaction. XRD results identified that all materials are pure phases with layered structure, indicating good structural compatibility between three layered compounds, LiNi1/2Mn 1/2O2, Li[Li1/3Mn2/3]O2, and LiCoO2. Li[Li1/3Mn2/3]O2 and LiCoO2 contents in these electrode materials presented important effects on structure and electrochemical properties. Our results demonstrated that the suitable structural integration of Li[Li1/3Mn 2/3]O2 and LiCoO2 components into LiNi 1/2Mn1/2O2 structure is a practicable way to prepare new electrode materials with the desired electrochemical performances even via a simple solid-state reaction. Among the materials investigated in this work, a reversible capacity of 180-200 mAh/g was obtained for the materials with 0.3 ≤ x + y ≤ 0.6 and excellent cycling performance was observed with a large x (x ≥ 0.25) value in the series of x + y = 0.5.

Original languageEnglish
JournalJournal of the Electrochemical Society
Volume152
Issue number1
DOIs
Publication statusPublished - 2005
Externally publishedYes

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electrode materials
Cathodes
cathodes
solid state
compatibility
phase diagrams
Solid state reactions
cycles
Electrodes
Electrochemical properties
Phase diagrams
Chemical analysis

ASJC Scopus subject areas

  • Electrochemistry
  • Surfaces, Coatings and Films
  • Surfaces and Interfaces

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Layered (1-x-y)LiNi1/2Mn1/2O2 · x Li[Li1/3Mn2/3] O2 · yLiCoO2 (0≤x = y≤0.3 and x + y = 0.5) cathode materials. / Zhang, Lianqi; Takada, Kazunori; Ohta, Narumi; Fukuda, Katsutoshi; Osada, Minoru; Wang, Lianzhou; Sasaki, Takayoshi; Watanabe, Mamoru.

In: Journal of the Electrochemical Society, Vol. 152, No. 1, 2005.

Research output: Contribution to journalArticle

Zhang, Lianqi ; Takada, Kazunori ; Ohta, Narumi ; Fukuda, Katsutoshi ; Osada, Minoru ; Wang, Lianzhou ; Sasaki, Takayoshi ; Watanabe, Mamoru. / Layered (1-x-y)LiNi1/2Mn1/2O2 · x Li[Li1/3Mn2/3] O2 · yLiCoO2 (0≤x = y≤0.3 and x + y = 0.5) cathode materials. In: Journal of the Electrochemical Society. 2005 ; Vol. 152, No. 1.
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abstract = "An exploration of new cathode materials along the two lines having the nominal compositions of (1 - x - y)LiNi1/2Mn1/2O 2 · x Li[Li1/3Mn2/3]O2 · yLiCoO2 (0 ≤ x = y ≤ 0.3 and x + y = 0.5) was performed in the phase diagram of LiNi1/2Mn1/2O 2-Li[Li1/3Mn2/3]O2-LiCoO 2 by a simple solid-state reaction. XRD results identified that all materials are pure phases with layered structure, indicating good structural compatibility between three layered compounds, LiNi1/2Mn 1/2O2, Li[Li1/3Mn2/3]O2, and LiCoO2. Li[Li1/3Mn2/3]O2 and LiCoO2 contents in these electrode materials presented important effects on structure and electrochemical properties. Our results demonstrated that the suitable structural integration of Li[Li1/3Mn 2/3]O2 and LiCoO2 components into LiNi 1/2Mn1/2O2 structure is a practicable way to prepare new electrode materials with the desired electrochemical performances even via a simple solid-state reaction. Among the materials investigated in this work, a reversible capacity of 180-200 mAh/g was obtained for the materials with 0.3 ≤ x + y ≤ 0.6 and excellent cycling performance was observed with a large x (x ≥ 0.25) value in the series of x + y = 0.5.",
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AU - Zhang, Lianqi

AU - Takada, Kazunori

AU - Ohta, Narumi

AU - Fukuda, Katsutoshi

AU - Osada, Minoru

AU - Wang, Lianzhou

AU - Sasaki, Takayoshi

AU - Watanabe, Mamoru

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AB - An exploration of new cathode materials along the two lines having the nominal compositions of (1 - x - y)LiNi1/2Mn1/2O 2 · x Li[Li1/3Mn2/3]O2 · yLiCoO2 (0 ≤ x = y ≤ 0.3 and x + y = 0.5) was performed in the phase diagram of LiNi1/2Mn1/2O 2-Li[Li1/3Mn2/3]O2-LiCoO 2 by a simple solid-state reaction. XRD results identified that all materials are pure phases with layered structure, indicating good structural compatibility between three layered compounds, LiNi1/2Mn 1/2O2, Li[Li1/3Mn2/3]O2, and LiCoO2. Li[Li1/3Mn2/3]O2 and LiCoO2 contents in these electrode materials presented important effects on structure and electrochemical properties. Our results demonstrated that the suitable structural integration of Li[Li1/3Mn 2/3]O2 and LiCoO2 components into LiNi 1/2Mn1/2O2 structure is a practicable way to prepare new electrode materials with the desired electrochemical performances even via a simple solid-state reaction. Among the materials investigated in this work, a reversible capacity of 180-200 mAh/g was obtained for the materials with 0.3 ≤ x + y ≤ 0.6 and excellent cycling performance was observed with a large x (x ≥ 0.25) value in the series of x + y = 0.5.

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