Layered Silicate-Organic Interncalation Compounds as Photofunctional Materials

Makoto Ogawa, Kazuyuki Kuroda, Chuzo Kato

    Research output: Contribution to journalArticle

    1 Citation (Scopus)

    Abstract

    Abstract: The alkylammonium-exchanged swellable layered clay minerals have been prepared and used as immobilizing media for photoactive organic compounds. Anthracene, pyrene and p-aminoazobenzene were incorporated into the interlayer spaces of the long-chain alkylammonium exchanged-smectites. It was revealed from the photoprocesses of the intercalated species that the adsorptive properties of the host materials varied depending on the arrangements of the interlayer alkylammoniumions. Besides the hydrophobic modification by long chain alkylammonium ions. 2-dimensional microporous structure was obtained by pillaring with tetramethylammonium ion.

    Original languageEnglish
    Pages (from-to)171-178
    Number of pages8
    JournalStudies in Surface Science and Catalysis
    Volume83
    Issue numberC
    DOIs
    Publication statusPublished - 1994

    Fingerprint

    Silicates
    organic compounds
    Organic compounds
    p-Aminoazobenzene
    interlayers
    silicates
    Ions
    Anthracene
    Pyrene
    pyrenes
    montmorillonite
    anthracene
    Clay minerals
    clays
    ions
    minerals
    Smectite
    pyrene
    tetramethylammonium

    ASJC Scopus subject areas

    • Condensed Matter Physics
    • Catalysis
    • Physical and Theoretical Chemistry
    • Materials Chemistry
    • Surfaces, Coatings and Films

    Cite this

    Layered Silicate-Organic Interncalation Compounds as Photofunctional Materials. / Ogawa, Makoto; Kuroda, Kazuyuki; Kato, Chuzo.

    In: Studies in Surface Science and Catalysis, Vol. 83, No. C, 1994, p. 171-178.

    Research output: Contribution to journalArticle

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