Linearity condition for orbital energies in density functional theory (II): Application to global hybrid functionals

Yutaka Imamura, Rie Kobayashi, Hiromi Nakai

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)

Abstract

We have previously proposed the linearity condition for orbital energies (LCOE) in density functional theory for constructing orbital-specific exchange-correlation (XC) functionals and reported promising results in the case of range-separated functionals [24]. This Letter applies the LCOE to global hybrid functionals of which the OS Hartree-Fock exchange portions are determined by the LCOE. The numerical assessment demonstrates accurate descriptions of core and valence orbital energies for all global hybrid functionals. Thus, the LCOE is generally an effective and essential condition for constructing XC functionals.

Original languageEnglish
Pages (from-to)130-135
Number of pages6
JournalChemical Physics Letters
Volume513
Issue number1-3
DOIs
Publication statusPublished - 2011 Sep 6

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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