Liquid chromatography-quadruple time of flight mass spectrometry analysis of products in degraded lithium-ion batteries

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Abstract

The electrode surfaces of degraded lithium-ion batteries (LIB) were analyzed by liquid chromatography-quadrupole time of flight mass spectrometry (LC-QTOF/MS). The solid-electrolyte interphase (SEI) layer influences the performance of LIBs. Therefore, we conducted a study aimed at clarifying the deterioration mechanism of LIBs by examining the components in the SEI before and after degradation due to cycling.We believe that the change in the mass transfer characteristics at the electrode interface influenced by SEI deterioration can be clarified via LC-QTOF/MS, which would allow elucidation of the deterioration mechanism. The analysis results showed that the degradation products contain multiple components, including polymers of carbonate compounds and phosphate esters, which are formed via electrochemical and chemical reactions, resulting in remarkably reduced capacity. The results suggest that LC-QTOF/MS is a valuable technique for the degradation analysis of LIBs.

Original languageEnglish
Pages (from-to)A2008-A2015
JournalJournal of the Electrochemical Society
Volume162
Issue number10
DOIs
Publication statusPublished - 2015

ASJC Scopus subject areas

  • Electrochemistry
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Renewable Energy, Sustainability and the Environment
  • Condensed Matter Physics

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