Lithium ion conductive oxysulfide, Li3PO4-Li 3PS4

Kazunori Takada, Minoru Osada, Narumi Ohta, Taro Inada, Akihisa Kajiyama, Hideki Sasaki, Shigeo Kondo, Mamoru Watanabe, Takayoshi Sasaki

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Ionic conductivity of Li3PS4 was enhanced by the two ways: quenching method and addition of Li3PO4. The quenching method froze its high-temperature phase partially down to room temperature and increased its ionic conductivity by three times. Addition of Li3PO4 resulted in the formation of a new metastable phase, the composition of which was considered to be around 0.25Li 3PO4-0.75Li3PS4. Its conductivity at room temperature was 7.3 × 10- 5 S cm- 1, which was about 100 times higher than that of Li3PS4.

Original languageEnglish
Pages (from-to)2355-2359
Number of pages5
JournalSolid State Ionics
Volume176
Issue number31-34
DOIs
Publication statusPublished - 2005 Oct
Externally publishedYes

Keywords

  • Lithium ion
  • Lithium phosphate
  • Oxysulfide
  • Solid electrolyte

ASJC Scopus subject areas

  • Electrochemistry
  • Physical and Theoretical Chemistry
  • Energy Engineering and Power Technology
  • Materials Chemistry
  • Condensed Matter Physics

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  • Cite this

    Takada, K., Osada, M., Ohta, N., Inada, T., Kajiyama, A., Sasaki, H., Kondo, S., Watanabe, M., & Sasaki, T. (2005). Lithium ion conductive oxysulfide, Li3PO4-Li 3PS4 Solid State Ionics, 176(31-34), 2355-2359. https://doi.org/10.1016/j.ssi.2005.03.023