Long-range lattice matching between (100)/(010) bismuth-layered perovskite structure and (101) rutile structure

Takayuki Watanabe, Keisuke Saito, Minoru Osada, Toshimasa Suzuki, Masayuki Fujimoto, Mamoru Yoshimoto, Atsushi Sasaki, Jin Liu, Masato Kakihana, Hiroshi Funakubo

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

a-/b-axis-oriented epitaxial bismuth layer-structured ferroelectric thin films were epitaxially grown on (101)-oriented oxide with rutile structure. The long-range lattice matching between the ferroelectric layer and the bottom rutile layer, particularly the number of rutile units facing one ferroelectric unit and the surface orientation, were discussed for (100)(010)Bi4Ti3O12//(101)TiO2 structure. Cross sectional transmission electron microscope analysis suggests that seven rutile units lie under one a-/b-axis-oriented Bi4Ti3O12 unit with lower misfit dislocation density comparing to eight rutile units by one Bi4Ti3O12 model. Based on this result, the surface orientation at the interface was simulated to give us an appropriate ion alignment model. The titanium layer in the (101)TiO2 structure is most likely to match with the oxygen layer in the a-/b-axis-oriented Bi4Ti3O12 film.

Original languageEnglish
Title of host publicationMaterials Research Society Symposium - Proceedings
EditorsD.Y. Kaufman, S Hoffmann-Eifert, S.R. Gilbert, S Aggarwal, M Shimizu
Pages69-74
Number of pages6
Volume748
Publication statusPublished - 2003
Externally publishedYes
EventFerroelectric Thin Films XI - Boston, MA, United States
Duration: 2002 Dec 22002 Dec 5

Other

OtherFerroelectric Thin Films XI
CountryUnited States
CityBoston, MA
Period02/12/202/12/5

Fingerprint

Bismuth
Perovskite
Ferroelectric materials
Ferroelectric thin films
Dislocations (crystals)
Electron microscopes
Titanium
Oxides
Oxygen
Ions
perovskite
titanium dioxide

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Watanabe, T., Saito, K., Osada, M., Suzuki, T., Fujimoto, M., Yoshimoto, M., ... Funakubo, H. (2003). Long-range lattice matching between (100)/(010) bismuth-layered perovskite structure and (101) rutile structure. In D. Y. Kaufman, S. Hoffmann-Eifert, S. R. Gilbert, S. Aggarwal, & M. Shimizu (Eds.), Materials Research Society Symposium - Proceedings (Vol. 748, pp. 69-74)

Long-range lattice matching between (100)/(010) bismuth-layered perovskite structure and (101) rutile structure. / Watanabe, Takayuki; Saito, Keisuke; Osada, Minoru; Suzuki, Toshimasa; Fujimoto, Masayuki; Yoshimoto, Mamoru; Sasaki, Atsushi; Liu, Jin; Kakihana, Masato; Funakubo, Hiroshi.

Materials Research Society Symposium - Proceedings. ed. / D.Y. Kaufman; S Hoffmann-Eifert; S.R. Gilbert; S Aggarwal; M Shimizu. Vol. 748 2003. p. 69-74.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Watanabe, T, Saito, K, Osada, M, Suzuki, T, Fujimoto, M, Yoshimoto, M, Sasaki, A, Liu, J, Kakihana, M & Funakubo, H 2003, Long-range lattice matching between (100)/(010) bismuth-layered perovskite structure and (101) rutile structure. in DY Kaufman, S Hoffmann-Eifert, SR Gilbert, S Aggarwal & M Shimizu (eds), Materials Research Society Symposium - Proceedings. vol. 748, pp. 69-74, Ferroelectric Thin Films XI, Boston, MA, United States, 02/12/2.
Watanabe T, Saito K, Osada M, Suzuki T, Fujimoto M, Yoshimoto M et al. Long-range lattice matching between (100)/(010) bismuth-layered perovskite structure and (101) rutile structure. In Kaufman DY, Hoffmann-Eifert S, Gilbert SR, Aggarwal S, Shimizu M, editors, Materials Research Society Symposium - Proceedings. Vol. 748. 2003. p. 69-74
Watanabe, Takayuki ; Saito, Keisuke ; Osada, Minoru ; Suzuki, Toshimasa ; Fujimoto, Masayuki ; Yoshimoto, Mamoru ; Sasaki, Atsushi ; Liu, Jin ; Kakihana, Masato ; Funakubo, Hiroshi. / Long-range lattice matching between (100)/(010) bismuth-layered perovskite structure and (101) rutile structure. Materials Research Society Symposium - Proceedings. editor / D.Y. Kaufman ; S Hoffmann-Eifert ; S.R. Gilbert ; S Aggarwal ; M Shimizu. Vol. 748 2003. pp. 69-74
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AU - Saito, Keisuke

AU - Osada, Minoru

AU - Suzuki, Toshimasa

AU - Fujimoto, Masayuki

AU - Yoshimoto, Mamoru

AU - Sasaki, Atsushi

AU - Liu, Jin

AU - Kakihana, Masato

AU - Funakubo, Hiroshi

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AB - a-/b-axis-oriented epitaxial bismuth layer-structured ferroelectric thin films were epitaxially grown on (101)-oriented oxide with rutile structure. The long-range lattice matching between the ferroelectric layer and the bottom rutile layer, particularly the number of rutile units facing one ferroelectric unit and the surface orientation, were discussed for (100)(010)Bi4Ti3O12//(101)TiO2 structure. Cross sectional transmission electron microscope analysis suggests that seven rutile units lie under one a-/b-axis-oriented Bi4Ti3O12 unit with lower misfit dislocation density comparing to eight rutile units by one Bi4Ti3O12 model. Based on this result, the surface orientation at the interface was simulated to give us an appropriate ion alignment model. The titanium layer in the (101)TiO2 structure is most likely to match with the oxygen layer in the a-/b-axis-oriented Bi4Ti3O12 film.

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