Low temperature catalytic reverse water gas shift reaction assisted by an electric field

Kazumasa Oshima, Tatsuya Shinagawa, Yukako Nogami, Ryo Manabe, Shuhei Ogo, Yasushi Sekine

Research output: Contribution to journalArticle

44 Citations (Scopus)

Abstract

Catalytic reverse water gas shift reaction was conducted in an electric field (denoted as E-RWGS) over various catalysts at low temperature as 423 K. A platinum catalyst supported on lanthanum doped zirconia (Pt/La-ZrO2) showed the highest yield (ca. 40%) for the E-RWGS reaction even at such low temperature condition. In contrast to a bare oxide catalyst, metal loading catalysts showed higher activities and efficiencies for the reaction. Roles of the impregnated platinum and doped lanthanum on the catalytic activity were investigated, and we found that loaded platinum worked as an active site for the E-RWGS reaction, and La doping stabilized the structure of ZrO2. The effect of the electric field was discussed based on thermodynamic evaluation and experimental results.

Original languageEnglish
Pages (from-to)27-32
Number of pages6
JournalCatalysis Today
Volume232
DOIs
Publication statusPublished - 2014 Sep 1

Fingerprint

Water gas shift
Platinum
Lanthanum
Electric fields
Catalysts
Catalyst activity
Catalyst supports
Zirconia
Temperature
Oxides
Metals
Doping (additives)
Thermodynamics

Keywords

  • Carbon dioxide
  • Catalytic reaction
  • Electric field
  • Reverse water gas shift

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Low temperature catalytic reverse water gas shift reaction assisted by an electric field. / Oshima, Kazumasa; Shinagawa, Tatsuya; Nogami, Yukako; Manabe, Ryo; Ogo, Shuhei; Sekine, Yasushi.

In: Catalysis Today, Vol. 232, 01.09.2014, p. 27-32.

Research output: Contribution to journalArticle

Oshima, Kazumasa ; Shinagawa, Tatsuya ; Nogami, Yukako ; Manabe, Ryo ; Ogo, Shuhei ; Sekine, Yasushi. / Low temperature catalytic reverse water gas shift reaction assisted by an electric field. In: Catalysis Today. 2014 ; Vol. 232. pp. 27-32.
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