Low-Temperature Direct Catalytic Hydrothermal Conversion of Biomass Cellulose to Light Hydrocarbons over Pt/Zeolite Catalysts

Shuhei Ogo, Yutaro Okuno, Hikaru Sekine, Shota Manabe, Tomohiro Yabe, Ayumu Onda, Yasushi Sekine

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Direct catalytic hydrothermal conversion of cellulose to C3+C4 hydrocarbons at a low temperature (443 K) over a Pt/zeolite catalyst without hydrogen or other expensive reagents was investigated. Pt supported on NH4 +-form ultra-stable Y-type (NH4-USY) zeolite catalyst, which showed the highest activity among the tested Pt/zeolite catalysts, has appropriate acidity and a suitable active Pt site. The C3+C4 hydrocarbon yield reached 14.5 C-% during the reaction over the Pt/NH4-USY catalyst at 443 K after 72 h of the reaction. Results showed that the acid strength of the zeolite support was an important factor affecting the cellulose decomposition activity. Because of their structural sensitivity, Pt/zeolite catalysts with Pt particles larger than 5 nm, including Pt/NH4-USY catalyst, showed higher TOF values than catalysts with Pt particles smaller than 5 nm.

Original languageEnglish
Pages (from-to)6201-6205
Number of pages5
JournalChemistrySelect
Volume2
Issue number22
DOIs
Publication statusPublished - 2017 Jan 1

Fingerprint

Zeolites
Hydrocarbons
Cellulose
Biomass
Catalysts
Temperature
Acidity
Hydrogen
Catalyst activity
Decomposition
Acids

Keywords

  • Biomass
  • Hydrocarbons
  • Hydrothermal reaction
  • Supported Pt catalyst
  • USY zeolite support

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Low-Temperature Direct Catalytic Hydrothermal Conversion of Biomass Cellulose to Light Hydrocarbons over Pt/Zeolite Catalysts. / Ogo, Shuhei; Okuno, Yutaro; Sekine, Hikaru; Manabe, Shota; Yabe, Tomohiro; Onda, Ayumu; Sekine, Yasushi.

In: ChemistrySelect, Vol. 2, No. 22, 01.01.2017, p. 6201-6205.

Research output: Contribution to journalArticle

Ogo, Shuhei ; Okuno, Yutaro ; Sekine, Hikaru ; Manabe, Shota ; Yabe, Tomohiro ; Onda, Ayumu ; Sekine, Yasushi. / Low-Temperature Direct Catalytic Hydrothermal Conversion of Biomass Cellulose to Light Hydrocarbons over Pt/Zeolite Catalysts. In: ChemistrySelect. 2017 ; Vol. 2, No. 22. pp. 6201-6205.
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