TY - JOUR
T1 - Low-temperature hydrogen production by highly efficient catalytic system assisted by an electric field
AU - Sekine, Yasushi
AU - Haraguchi, Masayuki
AU - Tomioka, Masahiko
AU - Matsukata, Masahiko
AU - Kikuchi, Eiichi
PY - 2010/3/25
Y1 - 2010/3/25
N2 - We investigated four catalytic reactions assisted with an electric field to promote catalytic activity, and we could achieve an effective process for hydrogen production at low temperatures, such as 423 K. In the presence of the electric field, four reactions of steam reforming of ethanol, decomposition of ethanol, water gas shift, and steam reforming of methane proceeded at very low temperature, such as 423 K, where a conventional catalytic reaction hardly proceeded. Conversion of reactant was greatly increased by the electric field, and apparent activation energies for these four reactions were lowered by the application of the electric field. This process can produce hydrogen and syngas by using a considerably small energy demand and has quick response.
AB - We investigated four catalytic reactions assisted with an electric field to promote catalytic activity, and we could achieve an effective process for hydrogen production at low temperatures, such as 423 K. In the presence of the electric field, four reactions of steam reforming of ethanol, decomposition of ethanol, water gas shift, and steam reforming of methane proceeded at very low temperature, such as 423 K, where a conventional catalytic reaction hardly proceeded. Conversion of reactant was greatly increased by the electric field, and apparent activation energies for these four reactions were lowered by the application of the electric field. This process can produce hydrogen and syngas by using a considerably small energy demand and has quick response.
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U2 - 10.1021/jp906137h
DO - 10.1021/jp906137h
M3 - Article
C2 - 20235604
AN - SCOPUS:77949851485
SN - 1089-5639
VL - 114
SP - 3824
EP - 3833
JO - Journal of Physical Chemistry A
JF - Journal of Physical Chemistry A
IS - 11
ER -