Mechanism of NiMoO4 formation during oxidative regeneration of resid HDS catalyst

Ryuichiro Iwamoto, Keisui Matsui, Atsushi Yamazaki

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The regeneration and reuse of resid HDS catalyst is an effective step in the establishment of environmentally friendly refinery. More effective regeneration of resid HDS catalyst requires the prevention of NiMoO4 formation. Aggregation of the active metal components as NiMoO4 during oxidative regeneration of residue HDS catalyst was studied. NiMoO4 was formed only on catalyst regenerated above 723 K. Increased temperature inside the catalyst due to the heat released by coke burning might be the main factor causing active metal aggregation during regeneration. Thus, aggregation of active metals might be prevented with milder regeneration conditions such as lower temperature and lower heating rate.

Original languageEnglish
Pages (from-to)211-215
Number of pages5
JournalJournal of The Japan Petroleum Institute
Volume52
Issue number4
DOIs
Publication statusPublished - 2009 Oct 1

Keywords

  • Coke burning
  • Micro x-ray diffraction
  • Nickel molybdenum oxide
  • Oxidative regeneration
  • Resid hydrodesulfurization catalyst
  • Vanadium accumulation

ASJC Scopus subject areas

  • Fuel Technology
  • Energy Engineering and Power Technology

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