MECHANISTIC ASPECTS OF OXYGEN ELECTROCHEMISTRY.

E. Yeager, Daniel Alberto Scherson, B. Simic-Glavaski

Research output: Contribution to journalConference article

14 Citations (Scopus)

Abstract

Various pathways for the electroreduction of O//2 and the corresponding electrocatalyst requirements are discussed. For the four-electron overall reduction of O//2 with solution phase peroxide as an intermediate, these requirements include strong interaction of oxygen species with the catalyst in a manner that promotes O-O bond cleavage and the proper redox potentials for the catalyst and its oxygen species adducts. Recent fundamental developments are reviewed with emphasis on the transition metal macrocyclic catalysts.

Original languageEnglish
Pages (from-to)247-270
Number of pages24
JournalProceedings - The Electrochemical Society
Volume84-12
Publication statusPublished - 1984 Dec 1
Externally publishedYes

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Electrochemistry
Catalysts
Oxygen
Electrocatalysts
Peroxides
Transition metals
Electrons

ASJC Scopus subject areas

  • Engineering(all)

Cite this

MECHANISTIC ASPECTS OF OXYGEN ELECTROCHEMISTRY. / Yeager, E.; Scherson, Daniel Alberto; Simic-Glavaski, B.

In: Proceedings - The Electrochemical Society, Vol. 84-12, 01.12.1984, p. 247-270.

Research output: Contribution to journalConference article

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