meso-tetrakis[o-(N-methyl)pyridinium]porphyrin ensembles with axially coordinated cyclodextrin-penetrating phenethylimidazole: Reversible dioxygen-binding in aqueous DMF solution

Teruyuki Komatsu, Shoichi Hayakawa, Eishun Tsuchida, Hiroyuki Nishide

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

α-Cyclodextrin (αCD)-penetrating 2-methyl-1-phenethylimidazole coordinates to the zinc(II) and iron(II) complexes of meso-tetrakis[o-(N-methyl)pyridinium] porphyrinate, giving non-covalently linked αCD-porphyrin ensembles; the iron(II) complex can reversibly bind and release dioxygen in aqueous DMF solution.

Original languageEnglish
Pages (from-to)50-51
Number of pages2
JournalChemical Communications
Volume9
Issue number1
DOIs
Publication statusPublished - 2003

ASJC Scopus subject areas

  • Chemistry(all)

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