Mesoporous Materials with Uniform Pore Size; Synthesis and Their Applications.

Yoshiaki Fukushima, Shinji Inagaki, Kazuyuki Kuroda, Kazuyuki Kuroda

    Research output: Contribution to journalArticle

    9 Citations (Scopus)

    Abstract

    We have proposed a folding sheet mechanism to form mesoporous crystal from a layered polysilicate, kanemite. This report reviews the structure of layered poly silicates, their intercalation properties, condensation reactions between the polysilicate layers, the mechanism of forming mesoporous materials (FSM) and their applications. SiO4-tetrahedral sheets and interlayer cations form sodium disilicate (Na2Si2O5) and kanemite (NaHSi2O5). An exchange for organic cations gave silicate/organic complexes. When we used kanemite as a host material, we observed a condensation reaction between the unit sheets besides the cation exchange. Removing the organic cations by calcination formed mesoporous materials. Cation exchange at pH = 12 folded the SiO4-tetrahedral sheets without the condensation. Following pH adjustment at 8.5 promoted the condensation between adjacent sheets and gave a silicate/organic complex with hexagonal symmetry. Highly ordered crystals with uniform pores were obtained by calcination at 550°C. We call this mechanism and materials folding sheets mechanism and folded sheets mesoporous materials (FSM), respectively. Complexes with layered structure were also made by using a surfactant with cylindrical shape, or by adding an alcohol. The mesoporous crystals (FSM) are expected to be useful as adsorbents, catalysts or host materials for making nano-cluster of metals or semi-conductors.

    Original languageEnglish
    Pages (from-to)327-333
    Number of pages7
    JournalNippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal
    Volume1995
    Issue number5
    DOIs
    Publication statusPublished - 1995

    Fingerprint

    Mesoporous materials
    Pore size
    Cations
    Silicates
    Positive ions
    Ion exchange
    Condensation reactions
    Calcination
    Crystals
    Condensation
    Crystal symmetry
    Intercalation
    Surface-Active Agents
    Adsorbents
    Alcohols
    Surface active agents
    Metals
    Sodium
    Catalysts

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Mesoporous Materials with Uniform Pore Size; Synthesis and Their Applications. / Fukushima, Yoshiaki; Inagaki, Shinji; Kuroda, Kazuyuki; Kuroda, Kazuyuki.

    In: Nippon Kagaku Kaishi / Chemical Society of Japan - Chemistry and Industrial Chemistry Journal, Vol. 1995, No. 5, 1995, p. 327-333.

    Research output: Contribution to journalArticle

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