Methylated-β-cyclodextrin mediated aqueous polymerization of hydrophobic methacrylic monomers

Phillip H. Madison, Timothy Edward Long

Research output: Contribution to journalConference article

Abstract

Aqueous polymerization of t-butyl methacrylate (tBuMA) and cyclohexyl methacrylate (CMA) mediated with methylated (1.8)-β-CD (MeCD) was carried out to determine the effects of initiator concentration, polymerization temperature, and monomer structure on the polymerization process, molecular weights, and molecular weight distributions of the final products. The blending of MeCD with various poly(alkyl methacrylate) homopolymers to form novel, optically shear carbohydrate/acrylic films was also examined. Overall, 24 hour complexation times resulted in solid complexes of tBuMA or CMA with MeCD.

Original languageEnglish
Pages (from-to)1836-1837
Number of pages2
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume41
Issue number2
Publication statusPublished - 2000 Aug 1
Externally publishedYes
EventWashington,DC. Meeting - Washington, DC, USA
Duration: 2000 Aug 202000 Aug 24

Fingerprint

Methacrylates
Cyclodextrins
Monomers
Polymerization
Molecular weight distribution
Carbohydrates
Homopolymerization
Complexation
Acrylics
Molecular weight
Temperature
butyl methacrylate

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Methylated-β-cyclodextrin mediated aqueous polymerization of hydrophobic methacrylic monomers. / Madison, Phillip H.; Long, Timothy Edward.

In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 41, No. 2, 01.08.2000, p. 1836-1837.

Research output: Contribution to journalConference article

@article{bf434f6dbec34f509c52ac0062ec6490,
title = "Methylated-β-cyclodextrin mediated aqueous polymerization of hydrophobic methacrylic monomers",
abstract = "Aqueous polymerization of t-butyl methacrylate (tBuMA) and cyclohexyl methacrylate (CMA) mediated with methylated (1.8)-β-CD (MeCD) was carried out to determine the effects of initiator concentration, polymerization temperature, and monomer structure on the polymerization process, molecular weights, and molecular weight distributions of the final products. The blending of MeCD with various poly(alkyl methacrylate) homopolymers to form novel, optically shear carbohydrate/acrylic films was also examined. Overall, 24 hour complexation times resulted in solid complexes of tBuMA or CMA with MeCD.",
author = "Madison, {Phillip H.} and Long, {Timothy Edward}",
year = "2000",
month = "8",
day = "1",
language = "English",
volume = "41",
pages = "1836--1837",
journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",
issn = "0032-3934",
number = "2",

}

TY - JOUR

T1 - Methylated-β-cyclodextrin mediated aqueous polymerization of hydrophobic methacrylic monomers

AU - Madison, Phillip H.

AU - Long, Timothy Edward

PY - 2000/8/1

Y1 - 2000/8/1

N2 - Aqueous polymerization of t-butyl methacrylate (tBuMA) and cyclohexyl methacrylate (CMA) mediated with methylated (1.8)-β-CD (MeCD) was carried out to determine the effects of initiator concentration, polymerization temperature, and monomer structure on the polymerization process, molecular weights, and molecular weight distributions of the final products. The blending of MeCD with various poly(alkyl methacrylate) homopolymers to form novel, optically shear carbohydrate/acrylic films was also examined. Overall, 24 hour complexation times resulted in solid complexes of tBuMA or CMA with MeCD.

AB - Aqueous polymerization of t-butyl methacrylate (tBuMA) and cyclohexyl methacrylate (CMA) mediated with methylated (1.8)-β-CD (MeCD) was carried out to determine the effects of initiator concentration, polymerization temperature, and monomer structure on the polymerization process, molecular weights, and molecular weight distributions of the final products. The blending of MeCD with various poly(alkyl methacrylate) homopolymers to form novel, optically shear carbohydrate/acrylic films was also examined. Overall, 24 hour complexation times resulted in solid complexes of tBuMA or CMA with MeCD.

UR - http://www.scopus.com/inward/record.url?scp=0034250146&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034250146&partnerID=8YFLogxK

M3 - Conference article

VL - 41

SP - 1836

EP - 1837

JO - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

SN - 0032-3934

IS - 2

ER -