Microwave-Assisted Template-Free Synthesis of Ni3(BO3)2(NOB) Hierarchical Nanoflowers for Electrocatalytic Oxygen Evolution

Sivasankara Rao Ede, Sengeni Anantharaj, Balasubramanian Subramanian, Arumugam Rathishkumar, Subrata Kundu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The construction of cost-effective, efficient, and sustainable catalytic systems for electrocatalytic hydrogen generation by water splitting is extremely important for future fuels globally. Herein, we have prepared nickel orthoborate (NOB) via simultaneous oxidation and reduction of nickel precursors and studied their role in oxygen evolution reaction (OER) for water electrolysis. In addition, the specific role of microwave irradiation and conventional stirring in the formation of NOB was also investigated with comparative assessment of their catalytic ability in electrochemical water splitting. It was found that NOB nanoflowers prepared via microwave irradiation exhibited better OER electrocatalyst than the ones prepared by conventional heating. Interestingly, the NOB nanoflowers outperformed the commercial NiO nanopowder under the identical experimental conditions in catalyzing OER. Morphological hierarchy and high Brunauer-Emmett-Teller specific surface area were attributed for their enhanced OER activity. A long run of 6 h chronopotentiometry analysis showed a negligible degradation in activity signified the high stability and endurance of NOB nanoflowers. The numbers of merits from the electrochemical characterizations revealed that NOB nanoflowers could be an alternate, efficient, and abundant OER electrocatalyst for bulk water electrolysis.

Original languageEnglish
Pages (from-to)6224-6233
Number of pages10
JournalEnergy and Fuels
Volume32
Issue number5
DOIs
Publication statusPublished - 2018 May 17
Externally publishedYes

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology

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