Miscibility in Binary Blends of Poly(vinylphenol) and Aromatic Polyesters

Christine J.T. Landry, Dennis J. Massa, David M. Teegarden, Michael R. Landry, P. Mark Henrichs, Ralph H. Colby, Timothy Edward Long

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

The effect of polymer structure on blend miscibility with poly(vinylphenol) (PVPh) has been studied for a variety of polyesters that contain aromatic moieties in their backbone. In general, polyesters derived from aliphatic diols showed evidence of interaction and miscibility with PVPh. However, immiscibility was observed if the aromatic content of the polyester was very high. Polyesters derived from aromaticcontaining diols generally showed little interaction and no miscibility with PVPh. Both solution-blending and melt-blending methods were utilized to prepare the blends. Good correlation between the thermal behavior and infrared results was observed. Miscibility of PVPh was observed with polyesters consisting of terephthalic acid and a mixture of ethylene glycol and 1,4-cyclohexanedimethanol moieties for copolymer compositions containing at least 20 mol % ethylene glycol. Miscibility was observed with poly(ethylene terephthalate), poly(butylene terephthalate), poly(2,2-dimethylpropylene terephthalate), poly(ethylene 2,6-naphthalenedicarboxylate), and a copolymer of terephthalic and pentanedioic acids with 1,2-propanediol and glycerol as well as with several cyclic aliphatic copolyesters containing 1,4-cyclohexanedicar boxy lie acid. Miscibility of PVPh was not observed with poly(l,4-cyclohexylene dimethylene terephthalate), Ardel D100, Eastman Kodar copolyester A150, several other polyesters with high aromatic content, and two liquid crystalline polyesters.

Original languageEnglish
Pages (from-to)6299-6307
Number of pages9
JournalMacromolecules
Volume26
Issue number23
DOIs
Publication statusPublished - 1993 Jan 1
Externally publishedYes

Fingerprint

Polyesters
Solubility
Ethylene Glycol
Ethylene glycol
Acids
Copolymers
Propylene Glycol
Polyethylene Terephthalates
Glycerol
Polyethylene terephthalates
Polymers
Ethylene
Crystalline materials
Infrared radiation
terephthalic acid
Liquids
Chemical analysis

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Landry, C. J. T., Massa, D. J., Teegarden, D. M., Landry, M. R., Henrichs, P. M., Colby, R. H., & Long, T. E. (1993). Miscibility in Binary Blends of Poly(vinylphenol) and Aromatic Polyesters. Macromolecules, 26(23), 6299-6307. https://doi.org/10.1021/ma00075a027

Miscibility in Binary Blends of Poly(vinylphenol) and Aromatic Polyesters. / Landry, Christine J.T.; Massa, Dennis J.; Teegarden, David M.; Landry, Michael R.; Henrichs, P. Mark; Colby, Ralph H.; Long, Timothy Edward.

In: Macromolecules, Vol. 26, No. 23, 01.01.1993, p. 6299-6307.

Research output: Contribution to journalArticle

Landry, CJT, Massa, DJ, Teegarden, DM, Landry, MR, Henrichs, PM, Colby, RH & Long, TE 1993, 'Miscibility in Binary Blends of Poly(vinylphenol) and Aromatic Polyesters', Macromolecules, vol. 26, no. 23, pp. 6299-6307. https://doi.org/10.1021/ma00075a027
Landry CJT, Massa DJ, Teegarden DM, Landry MR, Henrichs PM, Colby RH et al. Miscibility in Binary Blends of Poly(vinylphenol) and Aromatic Polyesters. Macromolecules. 1993 Jan 1;26(23):6299-6307. https://doi.org/10.1021/ma00075a027
Landry, Christine J.T. ; Massa, Dennis J. ; Teegarden, David M. ; Landry, Michael R. ; Henrichs, P. Mark ; Colby, Ralph H. ; Long, Timothy Edward. / Miscibility in Binary Blends of Poly(vinylphenol) and Aromatic Polyesters. In: Macromolecules. 1993 ; Vol. 26, No. 23. pp. 6299-6307.
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