Modulating electrochemical activity in polyaniline/titanium oxide hybrid nanostructured ultrathin films

Antonio F. Frau, Thomas J. Lane, Andrea E. Schlather, Jin Young Park, Rigoberto C. Advincula

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Hybrid and nanostructured ultrathin films of polyaniline (PANI) were fabricated using combined layer-by-layer (LbL) and surface sol-gel (SSG) processing with titanium oxide (TiOx) layers. This enabled modulation of the electrochemical and the doping-dedoping process of the electroactive conjugated polymer with respect to thickness, presence of another polyelectrolyte, and intercalation of the inorganic slabs. The structure, composition, and viscoelastic behavior were proven by UV-vis absorbance, FT-IR, XPS, and QCM-D measurements. Spectroelectrochemical behavior showed that the oxidative stability of the films brought about the nanostructure control of the LbL process. On the other hand, the presence of the inorganic layer resulted in preventing electron transfer based on quinoid to benzenoid, Q → B, transitions. Thus, pairing the LbL assembly and the SSG process yielded a highly ordered, tunable structure in which the electrochemical behavior was modulated and correlated with diffusion-related arguments (Cottrell equation) of a blocking effect of the sol-gel layer. Further studies will be made on evaluating possible applications in thin film battery and capacitor devices.

Original languageEnglish
Pages (from-to)5532-5542
Number of pages11
JournalIndustrial and Engineering Chemistry Research
Volume50
Issue number9
DOIs
Publication statusPublished - 2011 May 4
Externally publishedYes

Fingerprint

Ultrathin films
Titanium oxides
Polyaniline
Sol-gels
Conjugated polymers
Intercalation
Polyelectrolytes
Sol-gel process
Nanostructures
X ray photoelectron spectroscopy
Doping (additives)
Modulation
Electrons
Processing
Chemical analysis
polyaniline
titanium dioxide
Film capacitor

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

Modulating electrochemical activity in polyaniline/titanium oxide hybrid nanostructured ultrathin films. / Frau, Antonio F.; Lane, Thomas J.; Schlather, Andrea E.; Park, Jin Young; Advincula, Rigoberto C.

In: Industrial and Engineering Chemistry Research, Vol. 50, No. 9, 04.05.2011, p. 5532-5542.

Research output: Contribution to journalArticle

Frau, Antonio F. ; Lane, Thomas J. ; Schlather, Andrea E. ; Park, Jin Young ; Advincula, Rigoberto C. / Modulating electrochemical activity in polyaniline/titanium oxide hybrid nanostructured ultrathin films. In: Industrial and Engineering Chemistry Research. 2011 ; Vol. 50, No. 9. pp. 5532-5542.
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