Molecular cable-like 1-D iodic spiral chains covered with triple helices stabilized in guest-included chiral porous framework

Makoto Tadokoro, Yasuko Tanaka, Khoichiro Noguchi, Tomoaki Sugaya, Kyosuke Isoda

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The supramolecular crystal {[Pr(DMFA)] 3[Ni II(Hbim) 3] 2I} n with intricate chiral networks of [Ni II(Hbim) 3] - molecules is reported. It includes a cationic architecture as a guest, constructed from chiral nanotubes that penetrate I - chains with spiral channels wrapped by triple helices. The I - chains have AC conductivity in crystals like a molecular cable.

Original languageEnglish
Pages (from-to)7155-7157
Number of pages3
JournalChemical Communications
Volume48
Issue number57
DOIs
Publication statusPublished - 2012 Jul 21
Externally publishedYes

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ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

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