Molecular cable-like 1-D iodic spiral chains covered with triple helices stabilized in guest-included chiral porous framework

Makoto Tadokoro; Yasuko Tanaka; Khoichiro Noguchi; Tomoaki Sugaya; Kyosuke Isoda

doi:10.1039/c2cc32289g

Molecular cable-like 1-D iodic spiral chains covered with triple helices stabilized in guest-included chiral porous framework

Makoto Tadokoro^*, Yasuko Tanaka, Khoichiro Noguchi, Tomoaki Sugaya, Kyosuke Isoda

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The supramolecular crystal {[Pr(DMFA)] ₃[Ni ^II(Hbim) ₃] ₂I} _n with intricate chiral networks of [Ni ^II(Hbim) ₃] ^- molecules is reported. It includes a cationic architecture as a guest, constructed from chiral nanotubes that penetrate I ^- chains with spiral channels wrapped by triple helices. The I ^- chains have AC conductivity in crystals like a molecular cable.

Original language	English
Pages (from-to)	7155-7157
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	57
DOIs	https://doi.org/10.1039/c2cc32289g
Publication status	Published - 2012 Jul 21
Externally published	Yes

ASJC Scopus subject areas

Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Catalysis
Chemistry(all)

Access to Document

10.1039/c2cc32289g

Cite this

@article{7fbb571817e24340b78f9716c09aec58,

title = "Molecular cable-like 1-D iodic spiral chains covered with triple helices stabilized in guest-included chiral porous framework",

abstract = "The supramolecular crystal {[Pr(DMFA)] 3[Ni II(Hbim) 3] 2I} n with intricate chiral networks of [Ni II(Hbim) 3] - molecules is reported. It includes a cationic architecture as a guest, constructed from chiral nanotubes that penetrate I - chains with spiral channels wrapped by triple helices. The I - chains have AC conductivity in crystals like a molecular cable.",

author = "Makoto Tadokoro and Yasuko Tanaka and Khoichiro Noguchi and Tomoaki Sugaya and Kyosuke Isoda",

year = "2012",

month = jul,

day = "21",

doi = "10.1039/c2cc32289g",

language = "English",

volume = "48",

pages = "7155--7157",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "57",

}

TY - JOUR

T1 - Molecular cable-like 1-D iodic spiral chains covered with triple helices stabilized in guest-included chiral porous framework

AU - Tadokoro, Makoto

AU - Tanaka, Yasuko

AU - Noguchi, Khoichiro

AU - Sugaya, Tomoaki

AU - Isoda, Kyosuke

PY - 2012/7/21

Y1 - 2012/7/21

N2 - The supramolecular crystal {[Pr(DMFA)] 3[Ni II(Hbim) 3] 2I} n with intricate chiral networks of [Ni II(Hbim) 3] - molecules is reported. It includes a cationic architecture as a guest, constructed from chiral nanotubes that penetrate I - chains with spiral channels wrapped by triple helices. The I - chains have AC conductivity in crystals like a molecular cable.

AB - The supramolecular crystal {[Pr(DMFA)] 3[Ni II(Hbim) 3] 2I} n with intricate chiral networks of [Ni II(Hbim) 3] - molecules is reported. It includes a cationic architecture as a guest, constructed from chiral nanotubes that penetrate I - chains with spiral channels wrapped by triple helices. The I - chains have AC conductivity in crystals like a molecular cable.

UR - http://www.scopus.com/inward/record.url?scp=84862891787&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84862891787&partnerID=8YFLogxK

U2 - 10.1039/c2cc32289g

DO - 10.1039/c2cc32289g

M3 - Article

C2 - 22692569

AN - SCOPUS:84862891787

SN - 1359-7345

VL - 48

SP - 7155

EP - 7157

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Molecular cable-like 1-D iodic spiral chains covered with triple helices stabilized in guest-included chiral porous framework

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this