Molecular structure of a μ-Oxo chromium-iron complex: Rare example of a crystallographically characterized μ-Oxo heterometallic porphyrin

Kenichi Oyaizu, Agus Haryono, Yukio Nishimura, Kimihisa Yamamoto, Eishun Tsuchida

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    Abstract

    The crystal structure of a μ-oxo heterometallic porphyrin [(pip)(tpp)Cr(III)[OFe(III)[(tpp)] (pip = piperidine) not only confirmed the proposed oxidation state of chromium and iron atoms, but also revealed a unique coordination environment around chromium(III), which is substantially protruded from the porphyrin plane.

    Original languageEnglish
    Pages (from-to)1781-1784
    Number of pages4
    JournalBulletin of the Chemical Society of Japan
    Volume72
    Issue number8
    DOIs
    Publication statusPublished - 1999 Aug

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    ASJC Scopus subject areas

    • Chemistry(all)

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