Monolithic nanostructured silicate family templated by lyotropic liquid-crystalline nonionic surfactant mesophases

S. A. El-Safty, T. Hanaoka

Research output: Contribution to journalArticle

62 Citations (Scopus)

Abstract

A family of well-defined highly ordered mesoporous, silica materials (designated as HOM) was synthesized by using a high concentration of nonionic amphiphile of Brij 56 surfactant (C18EO10) as a structure-directing species. Monolithic nanostructures with regular arrays and extended periodicity were produced under acidic conditions and different ambient temperatures (25-45 °C). Liquid-crystal phases formed in aqueous/silica domains played an important role in controlling the monolithic structural morphology. The direct templating method enhanced the phase topology of Brij 56 with three-dimensional (3-D) accessible mesoporous silica of primitive-centered cubic Pn3m (HOM-7), 3-D hexagonal P63/mmc (HOM-3), and solid phase (S) with cubic Ia3d space group (HOM-5) mesophases. By adjustment of the phase behavior of Brij 56/TMOS mass ratio, ca. 35, 50, 70, and 75 wt %, the method yielded predictable mesophase structures of cubic spherical micellar Im3m (HOM-1), 2-D hexagonal P6mm (HOM-2), bicontinuous cubic Ia3d (HOM-5), and lamellar L∞ (HOM-6), respectively. A significant result was that the long-range ordered silica monoliths remained unchanged throughout the fast condensation of TMOS and removal of Brij 56 surfactant. Furthermore, all of the silica monoliths (HOM-types) had high surface area, uniform mesopore channels, well-defined morphological architectures, and large wall thickness of materials. HOM mesoporous molecular sieves were characterized by using powder X-ray diffraction, the Brunauer-Emmett-Teller method for nitrogen adsorption/desorption isotherms, transmission electron microscopy, and scanning electron microscopy. The results show that this direct template methodology can be used to successfully synthesize periodic mesoporous silica monoliths with a high degree of control over the mesopore morphology and the surfactant mesophase structures.

Original languageEnglish
Pages (from-to)2892-2902
Number of pages11
JournalChemistry of Materials
Volume15
Issue number15
DOIs
Publication statusPublished - 2003 Jul 29
Externally publishedYes

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Silicates
Nonionic surfactants
Cetomacrogol
Silicon Dioxide
Silica
Crystalline materials
Liquids
Surface-Active Agents
Surface active agents
Liquid Crystals
Amphiphiles
Molecular sieves
Phase behavior
X ray powder diffraction
Liquid crystals
Isotherms
Condensation
Nanostructures
Desorption
Nitrogen

ASJC Scopus subject areas

  • Materials Chemistry
  • Materials Science(all)

Cite this

Monolithic nanostructured silicate family templated by lyotropic liquid-crystalline nonionic surfactant mesophases. / El-Safty, S. A.; Hanaoka, T.

In: Chemistry of Materials, Vol. 15, No. 15, 29.07.2003, p. 2892-2902.

Research output: Contribution to journalArticle

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abstract = "A family of well-defined highly ordered mesoporous, silica materials (designated as HOM) was synthesized by using a high concentration of nonionic amphiphile of Brij 56 surfactant (C18EO10) as a structure-directing species. Monolithic nanostructures with regular arrays and extended periodicity were produced under acidic conditions and different ambient temperatures (25-45 °C). Liquid-crystal phases formed in aqueous/silica domains played an important role in controlling the monolithic structural morphology. The direct templating method enhanced the phase topology of Brij 56 with three-dimensional (3-D) accessible mesoporous silica of primitive-centered cubic Pn3m (HOM-7), 3-D hexagonal P63/mmc (HOM-3), and solid phase (S) with cubic Ia3d space group (HOM-5) mesophases. By adjustment of the phase behavior of Brij 56/TMOS mass ratio, ca. 35, 50, 70, and 75 wt {\%}, the method yielded predictable mesophase structures of cubic spherical micellar Im3m (HOM-1), 2-D hexagonal P6mm (HOM-2), bicontinuous cubic Ia3d (HOM-5), and lamellar L∞ (HOM-6), respectively. A significant result was that the long-range ordered silica monoliths remained unchanged throughout the fast condensation of TMOS and removal of Brij 56 surfactant. Furthermore, all of the silica monoliths (HOM-types) had high surface area, uniform mesopore channels, well-defined morphological architectures, and large wall thickness of materials. HOM mesoporous molecular sieves were characterized by using powder X-ray diffraction, the Brunauer-Emmett-Teller method for nitrogen adsorption/desorption isotherms, transmission electron microscopy, and scanning electron microscopy. The results show that this direct template methodology can be used to successfully synthesize periodic mesoporous silica monoliths with a high degree of control over the mesopore morphology and the surfactant mesophase structures.",
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