Mott-Hubbard transition in alkali ammonia fullerides

T. Takenobu, T. Muro, Y. Iwasa, T. Mitani

Research output: Contribution to journalArticle

Abstract

Monoammoniated alkali fullerides salt (NH3)K3-xRbxC60 (0 ≤ x ≤ 3), forming an isostructural orthorhombic series followed by a Mott-Hubbard type antiferromagnetic transition. The Néel temperature TN was found to first increase with the interfullerene spacing and then decreases for (NH3)Rb3C60, forming a maximum at 76 K. This behavior can not be understood by a simple localized electron model and provides direct evidence for the important role of electron correlation effects.

Original languageEnglish
Pages (from-to)1173-1174
Number of pages2
JournalSynthetic Metals
Volume121
Issue number1-3
DOIs
Publication statusPublished - 2001 Mar 15
Externally publishedYes

Fingerprint

fullerides
Electron correlations
Alkalies
Ammonia
ammonia
alkalies
Salts
Electrons
electrons
spacing
salts
Temperature
temperature

Keywords

  • Diffraction and scattering
  • Electron spin resonance
  • Fullerenes and derivatives
  • Magnetic phase transitions
  • X-ray emission

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Takenobu, T., Muro, T., Iwasa, Y., & Mitani, T. (2001). Mott-Hubbard transition in alkali ammonia fullerides. Synthetic Metals, 121(1-3), 1173-1174. https://doi.org/10.1016/S0379-6779(00)01234-0

Mott-Hubbard transition in alkali ammonia fullerides. / Takenobu, T.; Muro, T.; Iwasa, Y.; Mitani, T.

In: Synthetic Metals, Vol. 121, No. 1-3, 15.03.2001, p. 1173-1174.

Research output: Contribution to journalArticle

Takenobu, T, Muro, T, Iwasa, Y & Mitani, T 2001, 'Mott-Hubbard transition in alkali ammonia fullerides', Synthetic Metals, vol. 121, no. 1-3, pp. 1173-1174. https://doi.org/10.1016/S0379-6779(00)01234-0
Takenobu, T. ; Muro, T. ; Iwasa, Y. ; Mitani, T. / Mott-Hubbard transition in alkali ammonia fullerides. In: Synthetic Metals. 2001 ; Vol. 121, No. 1-3. pp. 1173-1174.
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