Multicomponent flourescence decay and molecular motion of diastereoisomeric styrene dimers on pico- and nano-second timescales

Hideyuki Itagaki, Kazuyuki Horie, Itaru Mita, Masakazu Washio, Seiichi Tagawa, Yoneho Tabata, Hisaya Sato, Yasuyuki Tanaka

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13 Citations (Scopus)

Abstract

The dynamic process of intramolecular excimer formation in meso and racemic 6,8-diphenyltridecanes (PS2), diastereoisomeric dimer model systems for polystyrene, was investigated by using picosecond pulse radiolysis. Monomeric flourescence of meso PS2 was found to decay with time constants of 3.5 and 0.5 ns.

Original languageEnglish
Pages (from-to)547-551
Number of pages5
JournalChemical Physics Letters
Volume120
Issue number6
DOIs
Publication statusPublished - 1985 Oct 25

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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